cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II)

The title compound, [Pd(C(18)H(14)PS)(2)], was synthesized by the reaction of (Ph(2)PC(6)H(4)SH) with [PdCl(2)(NCC(6)H(5))(2)] in a 2:1 molar ratio in the presence of a slight excess of NEt(3 )as base in dichloro­methane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The...

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Detalles Bibliográficos
Autores principales: Fierro-Arias, Jaime, Morales-Morales, David, Hernández-Ortega, Simón
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960604/
https://www.ncbi.nlm.nih.gov/pubmed/21201635
http://dx.doi.org/10.1107/S1600536808026718
Descripción
Sumario:The title compound, [Pd(C(18)H(14)PS)(2)], was synthesized by the reaction of (Ph(2)PC(6)H(4)SH) with [PdCl(2)(NCC(6)H(5))(2)] in a 2:1 molar ratio in the presence of a slight excess of NEt(3 )as base in dichloro­methane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The palladium center has a slightly distorted square-planar environment, with the two P—S chelating ligands adopting a cis configuration. The present structure is a pseudo-polymorph of [Pd(C(18)H(14)PS)(2)]·CH(2)Cl(2).

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