cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II)

The title compound, [Pd(C(18)H(14)PS)(2)], was synthesized by the reaction of (Ph(2)PC(6)H(4)SH) with [PdCl(2)(NCC(6)H(5))(2)] in a 2:1 molar ratio in the presence of a slight excess of NEt(3 )as base in dichloro­methane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The...

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Detalles Bibliográficos
Autores principales: Fierro-Arias, Jaime, Morales-Morales, David, Hernández-Ortega, Simón
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960604/
https://www.ncbi.nlm.nih.gov/pubmed/21201635
http://dx.doi.org/10.1107/S1600536808026718
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author Fierro-Arias, Jaime
Morales-Morales, David
Hernández-Ortega, Simón
author_facet Fierro-Arias, Jaime
Morales-Morales, David
Hernández-Ortega, Simón
author_sort Fierro-Arias, Jaime
collection PubMed
description The title compound, [Pd(C(18)H(14)PS)(2)], was synthesized by the reaction of (Ph(2)PC(6)H(4)SH) with [PdCl(2)(NCC(6)H(5))(2)] in a 2:1 molar ratio in the presence of a slight excess of NEt(3 )as base in dichloro­methane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The palladium center has a slightly distorted square-planar environment, with the two P—S chelating ligands adopting a cis configuration. The present structure is a pseudo-polymorph of [Pd(C(18)H(14)PS)(2)]·CH(2)Cl(2).
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spelling pubmed-29606042010-12-30 cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II) Fierro-Arias, Jaime Morales-Morales, David Hernández-Ortega, Simón Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(C(18)H(14)PS)(2)], was synthesized by the reaction of (Ph(2)PC(6)H(4)SH) with [PdCl(2)(NCC(6)H(5))(2)] in a 2:1 molar ratio in the presence of a slight excess of NEt(3 )as base in dichloro­methane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The palladium center has a slightly distorted square-planar environment, with the two P—S chelating ligands adopting a cis configuration. The present structure is a pseudo-polymorph of [Pd(C(18)H(14)PS)(2)]·CH(2)Cl(2). International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960604/ /pubmed/21201635 http://dx.doi.org/10.1107/S1600536808026718 Text en © Fierro-Arias et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fierro-Arias, Jaime
Morales-Morales, David
Hernández-Ortega, Simón
cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II)
title cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II)
title_full cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II)
title_fullStr cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II)
title_full_unstemmed cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II)
title_short cis-Bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) P,S]palladium(II)
title_sort cis-bis­[2-(diphenyl­phosphino)benzene­thiolato-κ(2) p,s]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960604/
https://www.ncbi.nlm.nih.gov/pubmed/21201635
http://dx.doi.org/10.1107/S1600536808026718
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AT moralesmoralesdavid cisbis2diphenylphosphinobenzenethiolatok2pspalladiumii
AT hernandezortegasimon cisbis2diphenylphosphinobenzenethiolatok2pspalladiumii

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