Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)

The asymmetric unit of the title compound, [ZnCl(2)(C(12)H(12)N(2))], contains two independent mol­ecules. The Zn(II) atoms are four-coordinated in distorted tetra­hedral configurations by two N atoms from 5,5′-dimethyl-2,2′-bipyridine and two terminal Cl atoms. In the crystal structure, inter­molec...

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Autores principales: Khalighi, Aida, Ahmadi, Roya, Amani, Vahid, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960607/
https://www.ncbi.nlm.nih.gov/pubmed/21201646
http://dx.doi.org/10.1107/S1600536808027104
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author Khalighi, Aida
Ahmadi, Roya
Amani, Vahid
Khavasi, Hamid Reza
author_facet Khalighi, Aida
Ahmadi, Roya
Amani, Vahid
Khavasi, Hamid Reza
author_sort Khalighi, Aida
collection PubMed
description The asymmetric unit of the title compound, [ZnCl(2)(C(12)H(12)N(2))], contains two independent mol­ecules. The Zn(II) atoms are four-coordinated in distorted tetra­hedral configurations by two N atoms from 5,5′-dimethyl-2,2′-bipyridine and two terminal Cl atoms. In the crystal structure, inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules. There are C—H⋯π contacts between the methyl groups and the pyridine and five-membered rings containing Zn(II) atoms; π–π contacts also exist between the pyridine rings [centroid–centroid distances = 3.665 (5) and 3.674 (5) Å].
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spelling pubmed-29606072010-12-30 Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II) Khalighi, Aida Ahmadi, Roya Amani, Vahid Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [ZnCl(2)(C(12)H(12)N(2))], contains two independent mol­ecules. The Zn(II) atoms are four-coordinated in distorted tetra­hedral configurations by two N atoms from 5,5′-dimethyl-2,2′-bipyridine and two terminal Cl atoms. In the crystal structure, inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules. There are C—H⋯π contacts between the methyl groups and the pyridine and five-membered rings containing Zn(II) atoms; π–π contacts also exist between the pyridine rings [centroid–centroid distances = 3.665 (5) and 3.674 (5) Å]. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960607/ /pubmed/21201646 http://dx.doi.org/10.1107/S1600536808027104 Text en © Khalighi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khalighi, Aida
Ahmadi, Roya
Amani, Vahid
Khavasi, Hamid Reza
Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)
title Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)
title_full Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)
title_fullStr Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)
title_full_unstemmed Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)
title_short Dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)
title_sort dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ(2) n,n′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960607/
https://www.ncbi.nlm.nih.gov/pubmed/21201646
http://dx.doi.org/10.1107/S1600536808027104
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AT amanivahid dichlorido55dimethyl22bipyridinek2nnzincii
AT khavasihamidreza dichlorido55dimethyl22bipyridinek2nnzincii

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