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{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate

In the title dinuclear complex, [NiLa(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octa­hedral geometry. The La(III) ion is coordinate...

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Detalles Bibliográficos
Autor principal: Liu, Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960610/
https://www.ncbi.nlm.nih.gov/pubmed/21201643
http://dx.doi.org/10.1107/S1600536808026986
Descripción
Sumario:In the title dinuclear complex, [NiLa(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octa­hedral geometry. The La(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the Schiff base ligand, forming a distorted bicapped square-anti­prismatic environment. In the crystal structure, inter­molecular O—H—O hydrogen bonds connect complex mol­ecules and methanol solvent mol­ecules, forming a two-dimensional network.