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{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate

In the title dinuclear complex, [NiLa(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octa­hedral geometry. The La(III) ion is coordinate...

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Detalles Bibliográficos
Autor principal: Liu, Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960610/
https://www.ncbi.nlm.nih.gov/pubmed/21201643
http://dx.doi.org/10.1107/S1600536808026986
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author Liu, Fei
author_facet Liu, Fei
author_sort Liu, Fei
collection PubMed
description In the title dinuclear complex, [NiLa(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octa­hedral geometry. The La(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the Schiff base ligand, forming a distorted bicapped square-anti­prismatic environment. In the crystal structure, inter­molecular O—H—O hydrogen bonds connect complex mol­ecules and methanol solvent mol­ecules, forming a two-dimensional network.
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spelling pubmed-29606102010-12-30 {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate Liu, Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [NiLa(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octa­hedral geometry. The La(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the Schiff base ligand, forming a distorted bicapped square-anti­prismatic environment. In the crystal structure, inter­molecular O—H—O hydrogen bonds connect complex mol­ecules and methanol solvent mol­ecules, forming a two-dimensional network. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960610/ /pubmed/21201643 http://dx.doi.org/10.1107/S1600536808026986 Text en © Fei Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Fei
{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate
title {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate
title_full {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate
title_fullStr {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate
title_full_unstemmed {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate
title_short {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)lanthanum(III) methanol disolvate
title_sort {μ-6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(ii)lanthanum(iii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960610/
https://www.ncbi.nlm.nih.gov/pubmed/21201643
http://dx.doi.org/10.1107/S1600536808026986
work_keys_str_mv AT liufei m66dimethoxy22propane13diylbisnitrilomethylidynediphenolatodimethanoltrinitratonickeliilanthanumiiimethanoldisolvate