Tetra-μ-2,5-difluoro­benzoato-bis­[(2,2′-bipyridine)(2,5-difluoro­benzoato)gadolinium(III)]

In the centrosymmetric title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(10)H(8)N(2))(2)], the asymmetric unit comprises one cation chelated by two 2,5-difluoro­benzoate and one 2,2′-bipyridine. Two cations are linked into dimers via three bridging carboxyl­ate groups from three 2,5-difluoro­benzoic aci...

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Detalles Bibliográficos
Autores principales: Li, Sheng, Zhang, Fu-Li, Tang, Kun, Ma, Yuan-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960618/
https://www.ncbi.nlm.nih.gov/pubmed/21201598
http://dx.doi.org/10.1107/S1600536808023507
Descripción
Sumario:In the centrosymmetric title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(10)H(8)N(2))(2)], the asymmetric unit comprises one cation chelated by two 2,5-difluoro­benzoate and one 2,2′-bipyridine. Two cations are linked into dimers via three bridging carboxyl­ate groups from three 2,5-difluoro­benzoic acid units. The Gd(III) ion is nine-coord­inated by seven O atoms and two N atoms.

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