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Tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(III)]
In the centrosymmetric title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(10)H(8)N(2))(2)], the asymmetric unit comprises one cation chelated by two 2,5-difluorobenzoate and one 2,2′-bipyridine. Two cations are linked into dimers via three bridging carboxylate groups from three 2,5-difluorobenzoic aci...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960618/ https://www.ncbi.nlm.nih.gov/pubmed/21201598 http://dx.doi.org/10.1107/S1600536808023507 |
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author | Li, Sheng Zhang, Fu-Li Tang, Kun Ma, Yuan-Fang |
author_facet | Li, Sheng Zhang, Fu-Li Tang, Kun Ma, Yuan-Fang |
author_sort | Li, Sheng |
collection | PubMed |
description | In the centrosymmetric title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(10)H(8)N(2))(2)], the asymmetric unit comprises one cation chelated by two 2,5-difluorobenzoate and one 2,2′-bipyridine. Two cations are linked into dimers via three bridging carboxylate groups from three 2,5-difluorobenzoic acid units. The Gd(III) ion is nine-coordinated by seven O atoms and two N atoms. |
format | Text |
id | pubmed-2960618 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29606182010-12-30 Tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(III)] Li, Sheng Zhang, Fu-Li Tang, Kun Ma, Yuan-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(10)H(8)N(2))(2)], the asymmetric unit comprises one cation chelated by two 2,5-difluorobenzoate and one 2,2′-bipyridine. Two cations are linked into dimers via three bridging carboxylate groups from three 2,5-difluorobenzoic acid units. The Gd(III) ion is nine-coordinated by seven O atoms and two N atoms. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960618/ /pubmed/21201598 http://dx.doi.org/10.1107/S1600536808023507 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Sheng Zhang, Fu-Li Tang, Kun Ma, Yuan-Fang Tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(III)] |
title | Tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(III)] |
title_full | Tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(III)] |
title_fullStr | Tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(III)] |
title_full_unstemmed | Tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(III)] |
title_short | Tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(III)] |
title_sort | tetra-μ-2,5-difluorobenzoato-bis[(2,2′-bipyridine)(2,5-difluorobenzoato)gadolinium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960618/ https://www.ncbi.nlm.nih.gov/pubmed/21201598 http://dx.doi.org/10.1107/S1600536808023507 |
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