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(2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II)
In the title compound, [Sr(C(10)H(15))(2)(C(10)H(8)N(2))], the Sr—N distances are 2.624 (3) and 2.676 (3) Å, the Sr⋯Cp ring centroid distances are 2.571 and 2.561 Å and the N—C—C—N torsion angle in the bipyridine ligand is −2.2 (4)°. Interestingly, the bipyridine ligand is tilted. The angle between...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960620/ https://www.ncbi.nlm.nih.gov/pubmed/21201592 http://dx.doi.org/10.1107/S1600536808024677 |
| Sumario: | In the title compound, [Sr(C(10)H(15))(2)(C(10)H(8)N(2))], the Sr—N distances are 2.624 (3) and 2.676 (3) Å, the Sr⋯Cp ring centroid distances are 2.571 and 2.561 Å and the N—C—C—N torsion angle in the bipyridine ligand is −2.2 (4)°. Interestingly, the bipyridine ligand is tilted. The angle between the plane defined by the Sr atom and the two bipyridyl N atoms and the plane defined by the 12 atoms of the bipyridine ligand is 10.7 (1)°. |
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