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(2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II)
In the title compound, [Sr(C(10)H(15))(2)(C(10)H(8)N(2))], the Sr—N distances are 2.624 (3) and 2.676 (3) Å, the Sr⋯Cp ring centroid distances are 2.571 and 2.561 Å and the N—C—C—N torsion angle in the bipyridine ligand is −2.2 (4)°. Interestingly, the bipyridine ligand is tilted. The angle between...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960620/ https://www.ncbi.nlm.nih.gov/pubmed/21201592 http://dx.doi.org/10.1107/S1600536808024677 |
| _version_ | 1782188784069115904 |
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| author | Kazhdan, Daniel Hu, Yung-Jin Kokai, Akos Levi, Zerubba Rozenel, Sergio |
| author_facet | Kazhdan, Daniel Hu, Yung-Jin Kokai, Akos Levi, Zerubba Rozenel, Sergio |
| author_sort | Kazhdan, Daniel |
| collection | PubMed |
| description | In the title compound, [Sr(C(10)H(15))(2)(C(10)H(8)N(2))], the Sr—N distances are 2.624 (3) and 2.676 (3) Å, the Sr⋯Cp ring centroid distances are 2.571 and 2.561 Å and the N—C—C—N torsion angle in the bipyridine ligand is −2.2 (4)°. Interestingly, the bipyridine ligand is tilted. The angle between the plane defined by the Sr atom and the two bipyridyl N atoms and the plane defined by the 12 atoms of the bipyridine ligand is 10.7 (1)°. |
| format | Text |
| id | pubmed-2960620 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29606202010-12-30 (2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II) Kazhdan, Daniel Hu, Yung-Jin Kokai, Akos Levi, Zerubba Rozenel, Sergio Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sr(C(10)H(15))(2)(C(10)H(8)N(2))], the Sr—N distances are 2.624 (3) and 2.676 (3) Å, the Sr⋯Cp ring centroid distances are 2.571 and 2.561 Å and the N—C—C—N torsion angle in the bipyridine ligand is −2.2 (4)°. Interestingly, the bipyridine ligand is tilted. The angle between the plane defined by the Sr atom and the two bipyridyl N atoms and the plane defined by the 12 atoms of the bipyridine ligand is 10.7 (1)°. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960620/ /pubmed/21201592 http://dx.doi.org/10.1107/S1600536808024677 Text en © Kazhdan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kazhdan, Daniel Hu, Yung-Jin Kokai, Akos Levi, Zerubba Rozenel, Sergio (2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II) |
| title | (2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II) |
| title_full | (2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II) |
| title_fullStr | (2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II) |
| title_full_unstemmed | (2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II) |
| title_short | (2,2-Bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(II) |
| title_sort | (2,2-bipyridyl)bis(η(5)-pentamethylcyclopentadienyl)strontium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960620/ https://www.ncbi.nlm.nih.gov/pubmed/21201592 http://dx.doi.org/10.1107/S1600536808024677 |
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