Aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) N,N′)zinc(II)

In the title complex, [Zn(C(10)H(7)N(2)O(2))(2)(H(2)O)], the Zn(II) ion and water O atom are located on a crystallographic twofold rotation axis and the metal atom assumes a distorted trigonal-bipyramidal ZnN(4)O coordination geometry. An intra­molecular O—H⋯O hydrogen bond occurs within the ligand...

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Detalles Bibliográficos
Autores principales: Zhang, Shi Guo, Hou, Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960646/
https://www.ncbi.nlm.nih.gov/pubmed/21201589
http://dx.doi.org/10.1107/S1600536808024495
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author Zhang, Shi Guo
Hou, Chao
author_facet Zhang, Shi Guo
Hou, Chao
author_sort Zhang, Shi Guo
collection PubMed
description In the title complex, [Zn(C(10)H(7)N(2)O(2))(2)(H(2)O)], the Zn(II) ion and water O atom are located on a crystallographic twofold rotation axis and the metal atom assumes a distorted trigonal-bipyramidal ZnN(4)O coordination geometry. An intra­molecular O—H⋯O hydrogen bond occurs within the ligand and inter­molecular O—H⋯O hydrogen bonds involving the water mol­ecule result in a sheet structure in the crystal structure. In addition, a short C—O⋯π contact between the O atom of the deprotonated hydroxyl group and a nearby pyridine ring [O⋯Cg = 3.977 (2) Å, where Cg is the centroid of the pyridine ring] is observed.
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spelling pubmed-29606462010-12-30 Aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) N,N′)zinc(II) Zhang, Shi Guo Hou, Chao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(10)H(7)N(2)O(2))(2)(H(2)O)], the Zn(II) ion and water O atom are located on a crystallographic twofold rotation axis and the metal atom assumes a distorted trigonal-bipyramidal ZnN(4)O coordination geometry. An intra­molecular O—H⋯O hydrogen bond occurs within the ligand and inter­molecular O—H⋯O hydrogen bonds involving the water mol­ecule result in a sheet structure in the crystal structure. In addition, a short C—O⋯π contact between the O atom of the deprotonated hydroxyl group and a nearby pyridine ring [O⋯Cg = 3.977 (2) Å, where Cg is the centroid of the pyridine ring] is observed. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960646/ /pubmed/21201589 http://dx.doi.org/10.1107/S1600536808024495 Text en © Zhang and Hou 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Shi Guo
Hou, Chao
Aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) N,N′)zinc(II)
title Aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) N,N′)zinc(II)
title_full Aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) N,N′)zinc(II)
title_fullStr Aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) N,N′)zinc(II)
title_full_unstemmed Aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) N,N′)zinc(II)
title_short Aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) N,N′)zinc(II)
title_sort aqua­bis(3′-hydr­oxy-2,2′-bipyridine-3-olato-κ(2) n,n′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960646/
https://www.ncbi.nlm.nih.gov/pubmed/21201589
http://dx.doi.org/10.1107/S1600536808024495
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