Di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) N,N′)copper(II)] dihydrate

The centrosymmetric title complex, [Cu(2)Br(4)(C(11)H(10)N(2)O(2))(2)]·2H(2)O, was one of three complexes isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 1:1 metal-to-ligand ratio of copper(II) with...

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Autores principales: Westcott, Barry L., Kopp-Vaughn, Kristin M., Daniels, Lee M., Zeller, Matthias
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960647/
https://www.ncbi.nlm.nih.gov/pubmed/21201584
http://dx.doi.org/10.1107/S1600536808024203
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author Westcott, Barry L.
Kopp-Vaughn, Kristin M.
Daniels, Lee M.
Zeller, Matthias
author_facet Westcott, Barry L.
Kopp-Vaughn, Kristin M.
Daniels, Lee M.
Zeller, Matthias
author_sort Westcott, Barry L.
collection PubMed
description The centrosymmetric title complex, [Cu(2)Br(4)(C(11)H(10)N(2)O(2))(2)]·2H(2)O, was one of three complexes isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 1:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand di-2-pyridylmethane­diol. The copper centers are bridged by bromide donors, leading to a Cu—Cu distance of 4.090 (6) Å. The crystals form as non-merohedral twins with two components related by a 180° rotation around the normal to [100]; the selected sample had a twin ratio of 0.63:0.37.
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spelling pubmed-29606472010-12-30 Di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) N,N′)copper(II)] dihydrate Westcott, Barry L. Kopp-Vaughn, Kristin M. Daniels, Lee M. Zeller, Matthias Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric title complex, [Cu(2)Br(4)(C(11)H(10)N(2)O(2))(2)]·2H(2)O, was one of three complexes isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 1:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand di-2-pyridylmethane­diol. The copper centers are bridged by bromide donors, leading to a Cu—Cu distance of 4.090 (6) Å. The crystals form as non-merohedral twins with two components related by a 180° rotation around the normal to [100]; the selected sample had a twin ratio of 0.63:0.37. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960647/ /pubmed/21201584 http://dx.doi.org/10.1107/S1600536808024203 Text en © Westcott et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Westcott, Barry L.
Kopp-Vaughn, Kristin M.
Daniels, Lee M.
Zeller, Matthias
Di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) N,N′)copper(II)] dihydrate
title Di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) N,N′)copper(II)] dihydrate
title_full Di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) N,N′)copper(II)] dihydrate
title_fullStr Di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) N,N′)copper(II)] dihydrate
title_full_unstemmed Di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) N,N′)copper(II)] dihydrate
title_short Di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) N,N′)copper(II)] dihydrate
title_sort di-μ-bromido-bis­[bromido(di-2-pyridylmethane­diol-κ(2) n,n′)copper(ii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960647/
https://www.ncbi.nlm.nih.gov/pubmed/21201584
http://dx.doi.org/10.1107/S1600536808024203
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AT danielsleem dimbromidobisbromidodi2pyridylmethanediolk2nncopperiidihydrate
AT zellermatthias dimbromidobisbromidodi2pyridylmethanediolk2nncopperiidihydrate

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