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cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate

In the title compound {systematic name: cis-bis­[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato-κ(2) N,N′]bis­(butyl­amine-κN)copper(II) penta­hydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butyl­amine and sdz = sulfadiazine(1−)], the copper(II) cat...

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Detalles Bibliográficos
Autores principales: Paşaoğlu, Hümeyra, Kaştaş, Gökhan, Heren, Zerrin, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960652/
https://www.ncbi.nlm.nih.gov/pubmed/21201631
http://dx.doi.org/10.1107/S1600536808026457
Descripción
Sumario:In the title compound {systematic name: cis-bis­[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato-κ(2) N,N′]bis­(butyl­amine-κN)copper(II) penta­hydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butyl­amine and sdz = sulfadiazine(1−)], the copper(II) cation is six-coordinated by four N atoms of two sulfadiazine ligands and two N atoms of butyl­amine ligands. The copper(II) ion and one of the water mol­ecules lie on twofold rotation axes. One of the butyl groups is disordered over two sites, with occupancies of 0.395 (8) and 0.605 (8). The geometry around the S atom is distorted tetra­hedral. The crystal structure involves inter­molecular N—H⋯N and N—H⋯O hydrogen bonds. N—H⋯N hydrogen bonds between sdz ligands lead to a sheet structure parallel to the ab plane.