Cargando…

cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate

In the title compound {systematic name: cis-bis­[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato-κ(2) N,N′]bis­(butyl­amine-κN)copper(II) penta­hydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butyl­amine and sdz = sulfadiazine(1−)], the copper(II) cat...

Descripción completa

Detalles Bibliográficos
Autores principales: Paşaoğlu, Hümeyra, Kaştaş, Gökhan, Heren, Zerrin, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960652/
https://www.ncbi.nlm.nih.gov/pubmed/21201631
http://dx.doi.org/10.1107/S1600536808026457
_version_ 1782188791618863104
author Paşaoğlu, Hümeyra
Kaştaş, Gökhan
Heren, Zerrin
Büyükgüngör, Orhan
author_facet Paşaoğlu, Hümeyra
Kaştaş, Gökhan
Heren, Zerrin
Büyükgüngör, Orhan
author_sort Paşaoğlu, Hümeyra
collection PubMed
description In the title compound {systematic name: cis-bis­[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato-κ(2) N,N′]bis­(butyl­amine-κN)copper(II) penta­hydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butyl­amine and sdz = sulfadiazine(1−)], the copper(II) cation is six-coordinated by four N atoms of two sulfadiazine ligands and two N atoms of butyl­amine ligands. The copper(II) ion and one of the water mol­ecules lie on twofold rotation axes. One of the butyl groups is disordered over two sites, with occupancies of 0.395 (8) and 0.605 (8). The geometry around the S atom is distorted tetra­hedral. The crystal structure involves inter­molecular N—H⋯N and N—H⋯O hydrogen bonds. N—H⋯N hydrogen bonds between sdz ligands lead to a sheet structure parallel to the ab plane.
format Text
id pubmed-2960652
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29606522010-12-30 cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate Paşaoğlu, Hümeyra Kaştaş, Gökhan Heren, Zerrin Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound {systematic name: cis-bis­[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato-κ(2) N,N′]bis­(butyl­amine-κN)copper(II) penta­hydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butyl­amine and sdz = sulfadiazine(1−)], the copper(II) cation is six-coordinated by four N atoms of two sulfadiazine ligands and two N atoms of butyl­amine ligands. The copper(II) ion and one of the water mol­ecules lie on twofold rotation axes. One of the butyl groups is disordered over two sites, with occupancies of 0.395 (8) and 0.605 (8). The geometry around the S atom is distorted tetra­hedral. The crystal structure involves inter­molecular N—H⋯N and N—H⋯O hydrogen bonds. N—H⋯N hydrogen bonds between sdz ligands lead to a sheet structure parallel to the ab plane. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960652/ /pubmed/21201631 http://dx.doi.org/10.1107/S1600536808026457 Text en © Paşaoğlu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Paşaoğlu, Hümeyra
Kaştaş, Gökhan
Heren, Zerrin
Büyükgüngör, Orhan
cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate
title cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate
title_full cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate
title_fullStr cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate
title_full_unstemmed cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate
title_short cis-Bis(butyl­amine-κN)bis­[sulfa­diazine(1−)-κ(2) N,N′]copper(II) penta­hydrate
title_sort cis-bis(butyl­amine-κn)bis­[sulfa­diazine(1−)-κ(2) n,n′]copper(ii) penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960652/
https://www.ncbi.nlm.nih.gov/pubmed/21201631
http://dx.doi.org/10.1107/S1600536808026457
work_keys_str_mv AT pasaogluhumeyra cisbisbutylamineknbissulfadiazine1k2nncopperiipentahydrate
AT kastasgokhan cisbisbutylamineknbissulfadiazine1k2nncopperiipentahydrate
AT herenzerrin cisbisbutylamineknbissulfadiazine1k2nncopperiipentahydrate
AT buyukgungororhan cisbisbutylamineknbissulfadiazine1k2nncopperiipentahydrate