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cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ(2) N,N′]copper(II) pentahydrate
In the title compound {systematic name: cis-bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato-κ(2) N,N′]bis(butylamine-κN)copper(II) pentahydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butylamine and sdz = sulfadiazine(1−)], the copper(II) cat...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960652/ https://www.ncbi.nlm.nih.gov/pubmed/21201631 http://dx.doi.org/10.1107/S1600536808026457 |
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author | Paşaoğlu, Hümeyra Kaştaş, Gökhan Heren, Zerrin Büyükgüngör, Orhan |
author_facet | Paşaoğlu, Hümeyra Kaştaş, Gökhan Heren, Zerrin Büyükgüngör, Orhan |
author_sort | Paşaoğlu, Hümeyra |
collection | PubMed |
description | In the title compound {systematic name: cis-bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato-κ(2) N,N′]bis(butylamine-κN)copper(II) pentahydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butylamine and sdz = sulfadiazine(1−)], the copper(II) cation is six-coordinated by four N atoms of two sulfadiazine ligands and two N atoms of butylamine ligands. The copper(II) ion and one of the water molecules lie on twofold rotation axes. One of the butyl groups is disordered over two sites, with occupancies of 0.395 (8) and 0.605 (8). The geometry around the S atom is distorted tetrahedral. The crystal structure involves intermolecular N—H⋯N and N—H⋯O hydrogen bonds. N—H⋯N hydrogen bonds between sdz ligands lead to a sheet structure parallel to the ab plane. |
format | Text |
id | pubmed-2960652 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29606522010-12-30 cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ(2) N,N′]copper(II) pentahydrate Paşaoğlu, Hümeyra Kaştaş, Gökhan Heren, Zerrin Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound {systematic name: cis-bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato-κ(2) N,N′]bis(butylamine-κN)copper(II) pentahydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butylamine and sdz = sulfadiazine(1−)], the copper(II) cation is six-coordinated by four N atoms of two sulfadiazine ligands and two N atoms of butylamine ligands. The copper(II) ion and one of the water molecules lie on twofold rotation axes. One of the butyl groups is disordered over two sites, with occupancies of 0.395 (8) and 0.605 (8). The geometry around the S atom is distorted tetrahedral. The crystal structure involves intermolecular N—H⋯N and N—H⋯O hydrogen bonds. N—H⋯N hydrogen bonds between sdz ligands lead to a sheet structure parallel to the ab plane. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960652/ /pubmed/21201631 http://dx.doi.org/10.1107/S1600536808026457 Text en © Paşaoğlu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Paşaoğlu, Hümeyra Kaştaş, Gökhan Heren, Zerrin Büyükgüngör, Orhan cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ(2) N,N′]copper(II) pentahydrate |
title |
cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ(2)
N,N′]copper(II) pentahydrate |
title_full |
cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ(2)
N,N′]copper(II) pentahydrate |
title_fullStr |
cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ(2)
N,N′]copper(II) pentahydrate |
title_full_unstemmed |
cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ(2)
N,N′]copper(II) pentahydrate |
title_short |
cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ(2)
N,N′]copper(II) pentahydrate |
title_sort | cis-bis(butylamine-κn)bis[sulfadiazine(1−)-κ(2)
n,n′]copper(ii) pentahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960652/ https://www.ncbi.nlm.nih.gov/pubmed/21201631 http://dx.doi.org/10.1107/S1600536808026457 |
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