BaCo(2)(AsO(4))(2)

Suitable single crystals of the title compound, barium dicobalt(II) bis­[orthoarsenate(V)], were prepared under hydro­thermal conditions. This phase belongs to a series of compounds with general formula AM (2)(XO(4))(2), where A = alkaline earth metal, M = Mg or a divalent first-row transition eleme...

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Detalles Bibliográficos
Autor principal: Đordević, Tamara
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960660/
https://www.ncbi.nlm.nih.gov/pubmed/21201566
http://dx.doi.org/10.1107/S1600536808025865
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author Đordević, Tamara
author_facet Đordević, Tamara
author_sort Đordević, Tamara
collection PubMed
description Suitable single crystals of the title compound, barium dicobalt(II) bis­[orthoarsenate(V)], were prepared under hydro­thermal conditions. This phase belongs to a series of compounds with general formula AM (2)(XO(4))(2), where A = alkaline earth metal, M = Mg or a divalent first-row transition element, and X = P, As or V. BaCo(2)(AsO(4))(2) is isotypic with BaNi(2)(XO(4))(2) (X = P, V or As) and is characterized by brucite-like sheets of edge-sharing CoO(6) octa­hedra (3 symmetry) parallel to (001), with one-third of the octa­hedral positions being vacant. The sheets are capped above and below by AsO(4) tetra­hedra (3 symmetry) and are inter­connected by distorted BaO(12) cubocta­hedra ([Image: see text] symmetry).
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spelling pubmed-29606602010-12-30 BaCo(2)(AsO(4))(2) Đordević, Tamara Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Suitable single crystals of the title compound, barium dicobalt(II) bis­[orthoarsenate(V)], were prepared under hydro­thermal conditions. This phase belongs to a series of compounds with general formula AM (2)(XO(4))(2), where A = alkaline earth metal, M = Mg or a divalent first-row transition element, and X = P, As or V. BaCo(2)(AsO(4))(2) is isotypic with BaNi(2)(XO(4))(2) (X = P, V or As) and is characterized by brucite-like sheets of edge-sharing CoO(6) octa­hedra (3 symmetry) parallel to (001), with one-third of the octa­hedral positions being vacant. The sheets are capped above and below by AsO(4) tetra­hedra (3 symmetry) and are inter­connected by distorted BaO(12) cubocta­hedra ([Image: see text] symmetry). International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960660/ /pubmed/21201566 http://dx.doi.org/10.1107/S1600536808025865 Text en © Tamara Đordević 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Đordević, Tamara
BaCo(2)(AsO(4))(2)
title BaCo(2)(AsO(4))(2)
title_full BaCo(2)(AsO(4))(2)
title_fullStr BaCo(2)(AsO(4))(2)
title_full_unstemmed BaCo(2)(AsO(4))(2)
title_short BaCo(2)(AsO(4))(2)
title_sort baco(2)(aso(4))(2)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960660/
https://www.ncbi.nlm.nih.gov/pubmed/21201566
http://dx.doi.org/10.1107/S1600536808025865
work_keys_str_mv AT đordevictamara baco2aso42

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