2-Nitro-p-phenyl­ene bis­(toluene­sulfonate)

In the mol­ecule of the title compound, C(20)H(17)NO(8)S(2), the two toluene rings are oriented at a dihedral angle of 3.65 (4)°, while the nitrophenyl ring is oriented at dihedral angles of 44.39 (3) and 47.44 (3)° with respect to the toluene rings. An intra­molecular C—H⋯O hydrogen bond results in...

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Detalles Bibliográficos
Autores principales: Ji, Xiujie, Cheng, Bowen, Song, Jun, Liu, Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960664/
https://www.ncbi.nlm.nih.gov/pubmed/21201792
http://dx.doi.org/10.1107/S1600536808026573
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author Ji, Xiujie
Cheng, Bowen
Song, Jun
Liu, Chao
author_facet Ji, Xiujie
Cheng, Bowen
Song, Jun
Liu, Chao
author_sort Ji, Xiujie
collection PubMed
description In the mol­ecule of the title compound, C(20)H(17)NO(8)S(2), the two toluene rings are oriented at a dihedral angle of 3.65 (4)°, while the nitrophenyl ring is oriented at dihedral angles of 44.39 (3) and 47.44 (3)° with respect to the toluene rings. An intra­molecular C—H⋯O hydrogen bond results in the formation of a five-membered ring, which adopts an envelope conformation. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules. There is a π–π contact between the toluene rings [centroid–centroid distance = 4.035 (1) Å].
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spelling pubmed-29606642010-12-30 2-Nitro-p-phenyl­ene bis­(toluene­sulfonate) Ji, Xiujie Cheng, Bowen Song, Jun Liu, Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(20)H(17)NO(8)S(2), the two toluene rings are oriented at a dihedral angle of 3.65 (4)°, while the nitrophenyl ring is oriented at dihedral angles of 44.39 (3) and 47.44 (3)° with respect to the toluene rings. An intra­molecular C—H⋯O hydrogen bond results in the formation of a five-membered ring, which adopts an envelope conformation. In the crystal structure, inter­molecular C—H⋯O hydrogen bonds link the mol­ecules. There is a π–π contact between the toluene rings [centroid–centroid distance = 4.035 (1) Å]. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960664/ /pubmed/21201792 http://dx.doi.org/10.1107/S1600536808026573 Text en © Ji et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ji, Xiujie
Cheng, Bowen
Song, Jun
Liu, Chao
2-Nitro-p-phenyl­ene bis­(toluene­sulfonate)
title 2-Nitro-p-phenyl­ene bis­(toluene­sulfonate)
title_full 2-Nitro-p-phenyl­ene bis­(toluene­sulfonate)
title_fullStr 2-Nitro-p-phenyl­ene bis­(toluene­sulfonate)
title_full_unstemmed 2-Nitro-p-phenyl­ene bis­(toluene­sulfonate)
title_short 2-Nitro-p-phenyl­ene bis­(toluene­sulfonate)
title_sort 2-nitro-p-phenyl­ene bis­(toluene­sulfonate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960664/
https://www.ncbi.nlm.nih.gov/pubmed/21201792
http://dx.doi.org/10.1107/S1600536808026573
work_keys_str_mv AT jixiujie 2nitropphenylenebistoluenesulfonate
AT chengbowen 2nitropphenylenebistoluenesulfonate
AT songjun 2nitropphenylenebistoluenesulfonate
AT liuchao 2nitropphenylenebistoluenesulfonate

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