Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(II)]

The title compound, [Cu(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)], is a centrosymmetric binuclear copper(II) complex, with a Cu⋯Cu separation of 6.136 (16) Å. The Cu atom displays a cis-CuN(2)O(2) square-planar geometry, although two long (> 2.43 Å) Cu⋯O contacts complete a distorted cis-CuN(2)O(4)...

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Detalles Bibliográficos
Autores principales: Guo, Hong-Xu, Liang, Min, Lin, Bin, Wang, Qing-Hua, Li, Xi-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960666/
https://www.ncbi.nlm.nih.gov/pubmed/21201617
http://dx.doi.org/10.1107/S160053680802583X
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author Guo, Hong-Xu
Liang, Min
Lin, Bin
Wang, Qing-Hua
Li, Xi-Zhong
author_facet Guo, Hong-Xu
Liang, Min
Lin, Bin
Wang, Qing-Hua
Li, Xi-Zhong
author_sort Guo, Hong-Xu
collection PubMed
description The title compound, [Cu(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)], is a centrosymmetric binuclear copper(II) complex, with a Cu⋯Cu separation of 6.136 (16) Å. The Cu atom displays a cis-CuN(2)O(2) square-planar geometry, although two long (> 2.43 Å) Cu⋯O contacts complete a distorted cis-CuN(2)O(4) octa­hedron. Extensive C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-29606662010-12-30 Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(II)] Guo, Hong-Xu Liang, Min Lin, Bin Wang, Qing-Hua Li, Xi-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)], is a centrosymmetric binuclear copper(II) complex, with a Cu⋯Cu separation of 6.136 (16) Å. The Cu atom displays a cis-CuN(2)O(2) square-planar geometry, although two long (> 2.43 Å) Cu⋯O contacts complete a distorted cis-CuN(2)O(4) octa­hedron. Extensive C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2008-08-16 /pmc/articles/PMC2960666/ /pubmed/21201617 http://dx.doi.org/10.1107/S160053680802583X Text en © Guo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Hong-Xu
Liang, Min
Lin, Bin
Wang, Qing-Hua
Li, Xi-Zhong
Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(II)]
title Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(II)]
title_full Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(II)]
title_fullStr Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(II)]
title_full_unstemmed Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(II)]
title_short Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(II)]
title_sort bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960666/
https://www.ncbi.nlm.nih.gov/pubmed/21201617
http://dx.doi.org/10.1107/S160053680802583X
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