N-(2,6-Diisopropyl­phen­yl)formamide

The title compound, C(13)H(19)NO, exhibits a non-planar structure in which the 2,6-diisopropyl­phenyl ring is tilted at a dihedral angle of 77.4 (1)° with respect to the formamide group. This is the largest dihedral angle known among structurally characterized formamides. The mol­ecules are linked v...

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Detalles Bibliográficos
Autores principales: Chitanda, Jackson M., Quail, J. Wilson, Foley, Stephen R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960669/
https://www.ncbi.nlm.nih.gov/pubmed/21201711
http://dx.doi.org/10.1107/S1600536808024811
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author Chitanda, Jackson M.
Quail, J. Wilson
Foley, Stephen R.
author_facet Chitanda, Jackson M.
Quail, J. Wilson
Foley, Stephen R.
author_sort Chitanda, Jackson M.
collection PubMed
description The title compound, C(13)H(19)NO, exhibits a non-planar structure in which the 2,6-diisopropyl­phenyl ring is tilted at a dihedral angle of 77.4 (1)° with respect to the formamide group. This is the largest dihedral angle known among structurally characterized formamides. The mol­ecules are linked via N—H⋯O hydrogen bonds, forming infinite chains which run along the b-axis directions.
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spelling pubmed-29606692010-12-30 N-(2,6-Diisopropyl­phen­yl)formamide Chitanda, Jackson M. Quail, J. Wilson Foley, Stephen R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(19)NO, exhibits a non-planar structure in which the 2,6-diisopropyl­phenyl ring is tilted at a dihedral angle of 77.4 (1)° with respect to the formamide group. This is the largest dihedral angle known among structurally characterized formamides. The mol­ecules are linked via N—H⋯O hydrogen bonds, forming infinite chains which run along the b-axis directions. International Union of Crystallography 2008-08-09 /pmc/articles/PMC2960669/ /pubmed/21201711 http://dx.doi.org/10.1107/S1600536808024811 Text en © Chitanda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chitanda, Jackson M.
Quail, J. Wilson
Foley, Stephen R.
N-(2,6-Diisopropyl­phen­yl)formamide
title N-(2,6-Diisopropyl­phen­yl)formamide
title_full N-(2,6-Diisopropyl­phen­yl)formamide
title_fullStr N-(2,6-Diisopropyl­phen­yl)formamide
title_full_unstemmed N-(2,6-Diisopropyl­phen­yl)formamide
title_short N-(2,6-Diisopropyl­phen­yl)formamide
title_sort n-(2,6-diisopropyl­phen­yl)formamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960669/
https://www.ncbi.nlm.nih.gov/pubmed/21201711
http://dx.doi.org/10.1107/S1600536808024811
work_keys_str_mv AT chitandajacksonm n26diisopropylphenylformamide
AT quailjwilson n26diisopropylphenylformamide
AT foleystephenr n26diisopropylphenylformamide

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