Hexaaqua­zinc(II) dichloride bis­(hexa­methyl­enetetramine) tetra­hydrate

The title compound, [Zn(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, has been prepared under mild hydro­thermal conditions. The Zn(II) atom, located on a centre of symmetry, is coordinated by six water mol­ecules in a distorted octa­hedral coordination geometry. The hexa­methyl­enetetra­mine mol­ecule is...

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Detalles Bibliográficos
Autores principales: Yao, Xin Jian, Xuan, Ya Wen, Wu, Wen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960671/
https://www.ncbi.nlm.nih.gov/pubmed/21201590
http://dx.doi.org/10.1107/S1600536808024793
Descripción
Sumario:The title compound, [Zn(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, has been prepared under mild hydro­thermal conditions. The Zn(II) atom, located on a centre of symmetry, is coordinated by six water mol­ecules in a distorted octa­hedral coordination geometry. The hexa­methyl­enetetra­mine mol­ecule is not coordinated to Zn(II) but links the Zn complexes via three O—H⋯N hydrogen bonds. The remaining N atom of the hexa­methyl­enetetra­mine mol­ecule is hydrogen-bonded to a solvent water mol­ecule. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds link the components into a three-dimensional network.

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