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2-{[4-(Phenyldiazenyl)phenyl]iminomethyl}phenol

The mol­ecule of the title compound, C(19)H(15)N(3)O, is approximately planar and displays a trans configuration with respect to the C=N and N=N double bonds. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. The dihedral angles between the hydroxy­phenyl ring and the phenyl and b...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza, Schiffers, Stefanie, Moghadam, Majid, Raithby, Paul R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960672/
https://www.ncbi.nlm.nih.gov/pubmed/21201827
http://dx.doi.org/10.1107/S1600536808027244
Descripción
Sumario:The mol­ecule of the title compound, C(19)H(15)N(3)O, is approximately planar and displays a trans configuration with respect to the C=N and N=N double bonds. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. The dihedral angles between the hydroxy­phenyl ring and the phenyl and benzene rings are 4.31 (8) and 6.60 (8)°, respectively. The dihedral angle between the phenyl and benzene rings linked by the azo group is 2.70 (8)°. The imino group is coplanar with the hydroxy­phenyl ring, as shown by the C—C—C—N torsion angle of −1.8 (2)°. The azo group is disordered over two position with refined site-occupancy factors of ca 0.87/0.13. In the crystal structure, mol­ecules are linked together by inter­molecular C—H⋯O inter­actions along the c axis and also are packed as one-dimensional extended chains down the b axis.