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catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]

The title complex, [Cu(2)Br(3)(C(11)H(9)N(2)O(2))](n), was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, d...

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Detalles Bibliográficos
Autores principales: Zeller, Matthias, Westcott, Barry L., Kopp-Vaughn, Kristin M., Hunter, Allen D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960673/
https://www.ncbi.nlm.nih.gov/pubmed/21201583
http://dx.doi.org/10.1107/S1600536808024197
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author Zeller, Matthias
Westcott, Barry L.
Kopp-Vaughn, Kristin M.
Hunter, Allen D.
author_facet Zeller, Matthias
Westcott, Barry L.
Kopp-Vaughn, Kristin M.
Hunter, Allen D.
author_sort Zeller, Matthias
collection PubMed
description The title complex, [Cu(2)Br(3)(C(11)H(9)N(2)O(2))](n), was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, di-2-pyridylmethane­diol. The two copper centers are bridged by a bromide ion and the alk­oxy O atom, and the Cu—Cu distance is 2.9801 (5) Å. The dimeric units are further linked by bromide ions, leading to a two-dimensional extended bridged structure. O—H⋯O hydrogen bonds are present in the crystal structure.
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spelling pubmed-29606732010-12-30 catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] Zeller, Matthias Westcott, Barry L. Kopp-Vaughn, Kristin M. Hunter, Allen D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)Br(3)(C(11)H(9)N(2)O(2))](n), was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, di-2-pyridylmethane­diol. The two copper centers are bridged by a bromide ion and the alk­oxy O atom, and the Cu—Cu distance is 2.9801 (5) Å. The dimeric units are further linked by bromide ions, leading to a two-dimensional extended bridged structure. O—H⋯O hydrogen bonds are present in the crystal structure. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960673/ /pubmed/21201583 http://dx.doi.org/10.1107/S1600536808024197 Text en © Zeller et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zeller, Matthias
Westcott, Barry L.
Kopp-Vaughn, Kristin M.
Hunter, Allen D.
catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
title catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
title_full catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
title_fullStr catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
title_full_unstemmed catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
title_short catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
title_sort catena-poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethano­lato-κ(4) n,o:o,n′)dicopper(ii)(cu—cu)]-di-μ-bromido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960673/
https://www.ncbi.nlm.nih.gov/pubmed/21201583
http://dx.doi.org/10.1107/S1600536808024197
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