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catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido]
The title complex, [Cu(2)Br(3)(C(11)H(9)N(2)O(2))](n), was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, d...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960673/ https://www.ncbi.nlm.nih.gov/pubmed/21201583 http://dx.doi.org/10.1107/S1600536808024197 |
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author | Zeller, Matthias Westcott, Barry L. Kopp-Vaughn, Kristin M. Hunter, Allen D. |
author_facet | Zeller, Matthias Westcott, Barry L. Kopp-Vaughn, Kristin M. Hunter, Allen D. |
author_sort | Zeller, Matthias |
collection | PubMed |
description | The title complex, [Cu(2)Br(3)(C(11)H(9)N(2)O(2))](n), was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, di-2-pyridylmethanediol. The two copper centers are bridged by a bromide ion and the alkoxy O atom, and the Cu—Cu distance is 2.9801 (5) Å. The dimeric units are further linked by bromide ions, leading to a two-dimensional extended bridged structure. O—H⋯O hydrogen bonds are present in the crystal structure. |
format | Text |
id | pubmed-2960673 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29606732010-12-30 catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] Zeller, Matthias Westcott, Barry L. Kopp-Vaughn, Kristin M. Hunter, Allen D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)Br(3)(C(11)H(9)N(2)O(2))](n), was one of three isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 2:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand, di-2-pyridylmethanediol. The two copper centers are bridged by a bromide ion and the alkoxy O atom, and the Cu—Cu distance is 2.9801 (5) Å. The dimeric units are further linked by bromide ions, leading to a two-dimensional extended bridged structure. O—H⋯O hydrogen bonds are present in the crystal structure. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960673/ /pubmed/21201583 http://dx.doi.org/10.1107/S1600536808024197 Text en © Zeller et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zeller, Matthias Westcott, Barry L. Kopp-Vaughn, Kristin M. Hunter, Allen D. catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4) N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
title |
catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4)
N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
title_full |
catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4)
N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
title_fullStr |
catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4)
N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
title_full_unstemmed |
catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4)
N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
title_short |
catena-Poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4)
N,O:O,N′)dicopper(II)(Cu—Cu)]-di-μ-bromido] |
title_sort | catena-poly[[μ-bromido-(μ-hydroxydi-2-pyridylmethanolato-κ(4)
n,o:o,n′)dicopper(ii)(cu—cu)]-di-μ-bromido] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960673/ https://www.ncbi.nlm.nih.gov/pubmed/21201583 http://dx.doi.org/10.1107/S1600536808024197 |
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