Bis(diphenyl­phospho­rothio­yl) tris­ulfide

In the title compound, C(24)H(20)P(2)S(5), the P atoms are arranged trans with respect to the S(3) group and the S=P—S—S systems have cisoid geometry, with an average S—P—S—S torsion angle of −56.7°. The dihedral angles between the two phenyl rings attached to the P atoms are 87.33 (12) and 75.67 (1...

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Detalles Bibliográficos
Autores principales: Kulcsar, Monika, Silvestru, Anca, Vonas, Marius
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960680/
https://www.ncbi.nlm.nih.gov/pubmed/21201673
http://dx.doi.org/10.1107/S1600536808024070
Descripción
Sumario:In the title compound, C(24)H(20)P(2)S(5), the P atoms are arranged trans with respect to the S(3) group and the S=P—S—S systems have cisoid geometry, with an average S—P—S—S torsion angle of −56.7°. The dihedral angles between the two phenyl rings attached to the P atoms are 87.33 (12) and 75.67 (10)°. In the crystal structure, the mol­ecules are linked into chains running parallel to the a axis by weak inter­molecular C—H⋯S hydrogen bonds. Centrosymmetrically related chains are further connected by π–π stacking inter­actions, with a centroid-to-centroid distance of 3.795 (5) Å.

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