Tris[tris­(ethane-1,2-diamine)cobalt(II)] bis­[octa­cyanidomolybdate(V)] dihydrate

In the title compound, [Co(II)(C(2)H(8)N(2))(3)](3)[Mo(V)(CN)(8)](2)·2H(2)O, N—H⋯N and N—H⋯O hydrogen-bonding inter­actions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-anti­prismatic shape, while the Co complexes show distorted octa­hedral geom...

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Detalles Bibliográficos
Autores principales: Chu, Chao-Xia, Zhou, Hu, Liu, Lang, Yuan, Ai-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960682/
https://www.ncbi.nlm.nih.gov/pubmed/21201606
http://dx.doi.org/10.1107/S1600536808024951
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author Chu, Chao-Xia
Zhou, Hu
Liu, Lang
Yuan, Ai-Hua
author_facet Chu, Chao-Xia
Zhou, Hu
Liu, Lang
Yuan, Ai-Hua
author_sort Chu, Chao-Xia
collection PubMed
description In the title compound, [Co(II)(C(2)H(8)N(2))(3)](3)[Mo(V)(CN)(8)](2)·2H(2)O, N—H⋯N and N—H⋯O hydrogen-bonding inter­actions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-anti­prismatic shape, while the Co complexes show distorted octa­hedral geometry with an occupancy of 50%. One of the Co atoms resides on a crystallographic inversion centre.
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spelling pubmed-29606822010-12-30 Tris[tris­(ethane-1,2-diamine)cobalt(II)] bis­[octa­cyanidomolybdate(V)] dihydrate Chu, Chao-Xia Zhou, Hu Liu, Lang Yuan, Ai-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(II)(C(2)H(8)N(2))(3)](3)[Mo(V)(CN)(8)](2)·2H(2)O, N—H⋯N and N—H⋯O hydrogen-bonding inter­actions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-anti­prismatic shape, while the Co complexes show distorted octa­hedral geometry with an occupancy of 50%. One of the Co atoms resides on a crystallographic inversion centre. International Union of Crystallography 2008-08-13 /pmc/articles/PMC2960682/ /pubmed/21201606 http://dx.doi.org/10.1107/S1600536808024951 Text en © Chu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chu, Chao-Xia
Zhou, Hu
Liu, Lang
Yuan, Ai-Hua
Tris[tris­(ethane-1,2-diamine)cobalt(II)] bis­[octa­cyanidomolybdate(V)] dihydrate
title Tris[tris­(ethane-1,2-diamine)cobalt(II)] bis­[octa­cyanidomolybdate(V)] dihydrate
title_full Tris[tris­(ethane-1,2-diamine)cobalt(II)] bis­[octa­cyanidomolybdate(V)] dihydrate
title_fullStr Tris[tris­(ethane-1,2-diamine)cobalt(II)] bis­[octa­cyanidomolybdate(V)] dihydrate
title_full_unstemmed Tris[tris­(ethane-1,2-diamine)cobalt(II)] bis­[octa­cyanidomolybdate(V)] dihydrate
title_short Tris[tris­(ethane-1,2-diamine)cobalt(II)] bis­[octa­cyanidomolybdate(V)] dihydrate
title_sort tris[tris­(ethane-1,2-diamine)cobalt(ii)] bis­[octa­cyanidomolybdate(v)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960682/
https://www.ncbi.nlm.nih.gov/pubmed/21201606
http://dx.doi.org/10.1107/S1600536808024951
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AT liulang tristrisethane12diaminecobaltiibisoctacyanidomolybdatevdihydrate
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