trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate

In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa­hedral environment, coordinated by four N atoms of the 4,7-diaza­decane-1,10-diamine ligand, one water mol­ecule and an F atom trans to water. The five-membered chelate ring is in a gauch...

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Detalles Bibliográficos
Autores principales: Choi, Jong-Ha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960685/
https://www.ncbi.nlm.nih.gov/pubmed/21201626
http://dx.doi.org/10.1107/S1600536808026081
Descripción
Sumario:In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa­hedral environment, coordinated by four N atoms of the 4,7-diaza­decane-1,10-diamine ligand, one water mol­ecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds.

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