trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate

In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa­hedral environment, coordinated by four N atoms of the 4,7-diaza­decane-1,10-diamine ligand, one water mol­ecule and an F atom trans to water. The five-membered chelate ring is in a gauch...

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Detalles Bibliográficos
Autores principales: Choi, Jong-Ha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960685/
https://www.ncbi.nlm.nih.gov/pubmed/21201626
http://dx.doi.org/10.1107/S1600536808026081
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author Choi, Jong-Ha
Lee, Uk
author_facet Choi, Jong-Ha
Lee, Uk
author_sort Choi, Jong-Ha
collection PubMed
description In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa­hedral environment, coordinated by four N atoms of the 4,7-diaza­decane-1,10-diamine ligand, one water mol­ecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds.
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spelling pubmed-29606852010-12-30 trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate Choi, Jong-Ha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa­hedral environment, coordinated by four N atoms of the 4,7-diaza­decane-1,10-diamine ligand, one water mol­ecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds. International Union of Crystallography 2008-08-20 /pmc/articles/PMC2960685/ /pubmed/21201626 http://dx.doi.org/10.1107/S1600536808026081 Text en © Choi and Lee 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Choi, Jong-Ha
Lee, Uk
trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate
title trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate
title_full trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate
title_fullStr trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate
title_full_unstemmed trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate
title_short trans-Aqua­(4,7-diaza­decane-1,10-diamine-κ(4) N)fluoridochromium(III) bis­(perchlorate) monohydrate
title_sort trans-aqua­(4,7-diaza­decane-1,10-diamine-κ(4) n)fluoridochromium(iii) bis­(perchlorate) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960685/
https://www.ncbi.nlm.nih.gov/pubmed/21201626
http://dx.doi.org/10.1107/S1600536808026081
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