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catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2) N (3):N (3′)]] dinitrate]
In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octahedral environment by four N atoms from four different 1,1′-butane-1,4-diyldiimidazole ligands and two O atoms from the two water molecules. Bridging...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960687/ https://www.ncbi.nlm.nih.gov/pubmed/21201651 http://dx.doi.org/10.1107/S1600536808027281 |
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author | Wang, Xiao-Feng Wang, Jin-Feng Liu, Xiao-Yang |
author_facet | Wang, Xiao-Feng Wang, Jin-Feng Liu, Xiao-Yang |
author_sort | Wang, Xiao-Feng |
collection | PubMed |
description | In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octahedral environment by four N atoms from four different 1,1′-butane-1,4-diyldiimidazole ligands and two O atoms from the two water molecules. Bridging by the ligands results in a ribbon structure. Adjacent ribbons are linked to the nitrate anions via O—H⋯O hydrogen bonds, forming layers. One nitrate O atom is disordered equally over two positions. |
format | Text |
id | pubmed-2960687 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29606872010-12-30 catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2) N (3):N (3′)]] dinitrate] Wang, Xiao-Feng Wang, Jin-Feng Liu, Xiao-Yang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octahedral environment by four N atoms from four different 1,1′-butane-1,4-diyldiimidazole ligands and two O atoms from the two water molecules. Bridging by the ligands results in a ribbon structure. Adjacent ribbons are linked to the nitrate anions via O—H⋯O hydrogen bonds, forming layers. One nitrate O atom is disordered equally over two positions. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960687/ /pubmed/21201651 http://dx.doi.org/10.1107/S1600536808027281 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Xiao-Feng Wang, Jin-Feng Liu, Xiao-Yang catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2) N (3):N (3′)]] dinitrate] |
title |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dinitrate] |
title_full |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dinitrate] |
title_fullStr |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dinitrate] |
title_full_unstemmed |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dinitrate] |
title_short |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dinitrate] |
title_sort | catena-poly[[[diaquacopper(ii)]-bis[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
n
(3):n
(3′)]] dinitrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960687/ https://www.ncbi.nlm.nih.gov/pubmed/21201651 http://dx.doi.org/10.1107/S1600536808027281 |
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