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Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN (1))zinc(II)
The title compound, [Zn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Zn(II) atom lying on an inversion center. It contains two 4-bromobenzoate, two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the equa...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960695/ https://www.ncbi.nlm.nih.gov/pubmed/21201650 http://dx.doi.org/10.1107/S1600536808027074 |
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author | Öztürk, Aslı Hökelek, Tuncer Özbek, Fureya Elif Necefoğlu, Hacali |
author_facet | Öztürk, Aslı Hökelek, Tuncer Özbek, Fureya Elif Necefoğlu, Hacali |
author_sort | Öztürk, Aslı |
collection | PubMed |
description | The title compound, [Zn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Zn(II) atom lying on an inversion center. It contains two 4-bromobenzoate, two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the distorted octahedral geometry is completed by two N atoms in the axial positions. The methyl group of one of the ethyl groups is disordered over two positions, with occupancies of ca 0.65 and 0.35. The two aromatic rings are oriented at an angle of 77.22 (14)°. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into chains along the a axis. |
format | Text |
id | pubmed-2960695 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29606952010-12-30 Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN (1))zinc(II) Öztürk, Aslı Hökelek, Tuncer Özbek, Fureya Elif Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Zn(II) atom lying on an inversion center. It contains two 4-bromobenzoate, two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the distorted octahedral geometry is completed by two N atoms in the axial positions. The methyl group of one of the ethyl groups is disordered over two positions, with occupancies of ca 0.65 and 0.35. The two aromatic rings are oriented at an angle of 77.22 (14)°. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into chains along the a axis. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960695/ /pubmed/21201650 http://dx.doi.org/10.1107/S1600536808027074 Text en © Öztürk et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Öztürk, Aslı Hökelek, Tuncer Özbek, Fureya Elif Necefoğlu, Hacali Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN (1))zinc(II) |
title | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN
(1))zinc(II) |
title_full | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN
(1))zinc(II) |
title_fullStr | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN
(1))zinc(II) |
title_full_unstemmed | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN
(1))zinc(II) |
title_short | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN
(1))zinc(II) |
title_sort | diaquabis(4-bromobenzoato-κo)bis(n,n′-diethylnicotinamide-κn
(1))zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960695/ https://www.ncbi.nlm.nih.gov/pubmed/21201650 http://dx.doi.org/10.1107/S1600536808027074 |
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