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Diaquabis(4-bromo­benzoato-κO)­bis(N,N′-diethyl­nicotinamide-κN (1))zinc(II)

The title compound, [Zn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Zn(II) atom lying on an inversion center. It contains two 4-bromo­benzoate, two diethyl­nicotinamide ligands and two water mol­ecules, all of which are monodentate. The four O atoms in the equa...

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Autores principales: Öztürk, Aslı, Hökelek, Tuncer, Özbek, Fureya Elif, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960695/
https://www.ncbi.nlm.nih.gov/pubmed/21201650
http://dx.doi.org/10.1107/S1600536808027074
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author Öztürk, Aslı
Hökelek, Tuncer
Özbek, Fureya Elif
Necefoğlu, Hacali
author_facet Öztürk, Aslı
Hökelek, Tuncer
Özbek, Fureya Elif
Necefoğlu, Hacali
author_sort Öztürk, Aslı
collection PubMed
description The title compound, [Zn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Zn(II) atom lying on an inversion center. It contains two 4-bromo­benzoate, two diethyl­nicotinamide ligands and two water mol­ecules, all of which are monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the distorted octa­hedral geometry is completed by two N atoms in the axial positions. The methyl group of one of the ethyl groups is disordered over two positions, with occupancies of ca 0.65 and 0.35. The two aromatic rings are oriented at an angle of 77.22 (14)°. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into chains along the a axis.
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spelling pubmed-29606952010-12-30 Diaquabis(4-bromo­benzoato-κO)­bis(N,N′-diethyl­nicotinamide-κN (1))zinc(II) Öztürk, Aslı Hökelek, Tuncer Özbek, Fureya Elif Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Zn(II) atom lying on an inversion center. It contains two 4-bromo­benzoate, two diethyl­nicotinamide ligands and two water mol­ecules, all of which are monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the distorted octa­hedral geometry is completed by two N atoms in the axial positions. The methyl group of one of the ethyl groups is disordered over two positions, with occupancies of ca 0.65 and 0.35. The two aromatic rings are oriented at an angle of 77.22 (14)°. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into chains along the a axis. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960695/ /pubmed/21201650 http://dx.doi.org/10.1107/S1600536808027074 Text en © Öztürk et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Öztürk, Aslı
Hökelek, Tuncer
Özbek, Fureya Elif
Necefoğlu, Hacali
Diaquabis(4-bromo­benzoato-κO)­bis(N,N′-diethyl­nicotinamide-κN (1))zinc(II)
title Diaquabis(4-bromo­benzoato-κO)­bis(N,N′-diethyl­nicotinamide-κN (1))zinc(II)
title_full Diaquabis(4-bromo­benzoato-κO)­bis(N,N′-diethyl­nicotinamide-κN (1))zinc(II)
title_fullStr Diaquabis(4-bromo­benzoato-κO)­bis(N,N′-diethyl­nicotinamide-κN (1))zinc(II)
title_full_unstemmed Diaquabis(4-bromo­benzoato-κO)­bis(N,N′-diethyl­nicotinamide-κN (1))zinc(II)
title_short Diaquabis(4-bromo­benzoato-κO)­bis(N,N′-diethyl­nicotinamide-κN (1))zinc(II)
title_sort diaquabis(4-bromo­benzoato-κo)­bis(n,n′-diethyl­nicotinamide-κn (1))zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960695/
https://www.ncbi.nlm.nih.gov/pubmed/21201650
http://dx.doi.org/10.1107/S1600536808027074
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