3,5-Dimethyl-1-(2-pyridylcarbon­yl)-5-[(2-pyridylcarbon­yl)hydrazino]-2-pyrazoline methanol hemisolvate

The title compound, C(17)H(18)N(6)O(2)·0.5CH(3)OH, exists in the double keto form and adopts a highly puckered geometry, stabilized by intra­molecular N—H⋯O and N—H⋯N hydrogen bonds. Inter­molecular N—H⋯N hydrogen bonds and π–π stacking inter­actions [centroid–centroid separation = 3.654 (1) Å] asse...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Yuting, Yang, Hua, Li, Dacheng, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960697/
https://www.ncbi.nlm.nih.gov/pubmed/21201813
http://dx.doi.org/10.1107/S1600536808027335
Descripción
Sumario:The title compound, C(17)H(18)N(6)O(2)·0.5CH(3)OH, exists in the double keto form and adopts a highly puckered geometry, stabilized by intra­molecular N—H⋯O and N—H⋯N hydrogen bonds. Inter­molecular N—H⋯N hydrogen bonds and π–π stacking inter­actions [centroid–centroid separation = 3.654 (1) Å] assemble the mol­ecules into chains running in the [111] direction. The methanol solvent mol­ecule is disordered over two sites related by inversion and forms a bifurcated O—H⋯(N,O) hydrogen bond.

Ejemplares similares