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2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide
The title Schiff base compound, C(19)H(16)N(2)O(3), prepared by the reaction of 2-methoxy-1-naphthylaldehyde and 2-hydroxybenzohydrazide, crystallizes with two independent molecules in the asymmetric unit. Each molecule exists in a trans configuration with respect to the methylidene group. The...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960698/ https://www.ncbi.nlm.nih.gov/pubmed/21201804 http://dx.doi.org/10.1107/S1600536808026962 |
Sumario: | The title Schiff base compound, C(19)H(16)N(2)O(3), prepared by the reaction of 2-methoxy-1-naphthylaldehyde and 2-hydroxybenzohydrazide, crystallizes with two independent molecules in the asymmetric unit. Each molecule exists in a trans configuration with respect to the methylidene group. The naphthyl ring system make dihedral angles of 65.0 (2)° and 55.8 (2)° with the planes of the benzene rings. Intramolecular N—H⋯O and O—H⋯O hydrogen bonds help to stabilize the molecular conformations. In the crystal structure, molecules are linked into one-dimensional chains parallel to the c axis by intermolecular O—H⋯N and O—H⋯O hydrogen bonds. |
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