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2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide
The title Schiff base compound, C(19)H(16)N(2)O(3), prepared by the reaction of 2-methoxy-1-naphthylaldehyde and 2-hydroxybenzohydrazide, crystallizes with two independent molecules in the asymmetric unit. Each molecule exists in a trans configuration with respect to the methylidene group. The...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960698/ https://www.ncbi.nlm.nih.gov/pubmed/21201804 http://dx.doi.org/10.1107/S1600536808026962 |
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author | Qiu, Xiao-Yang |
author_facet | Qiu, Xiao-Yang |
author_sort | Qiu, Xiao-Yang |
collection | PubMed |
description | The title Schiff base compound, C(19)H(16)N(2)O(3), prepared by the reaction of 2-methoxy-1-naphthylaldehyde and 2-hydroxybenzohydrazide, crystallizes with two independent molecules in the asymmetric unit. Each molecule exists in a trans configuration with respect to the methylidene group. The naphthyl ring system make dihedral angles of 65.0 (2)° and 55.8 (2)° with the planes of the benzene rings. Intramolecular N—H⋯O and O—H⋯O hydrogen bonds help to stabilize the molecular conformations. In the crystal structure, molecules are linked into one-dimensional chains parallel to the c axis by intermolecular O—H⋯N and O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2960698 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29606982010-12-30 2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide Qiu, Xiao-Yang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(19)H(16)N(2)O(3), prepared by the reaction of 2-methoxy-1-naphthylaldehyde and 2-hydroxybenzohydrazide, crystallizes with two independent molecules in the asymmetric unit. Each molecule exists in a trans configuration with respect to the methylidene group. The naphthyl ring system make dihedral angles of 65.0 (2)° and 55.8 (2)° with the planes of the benzene rings. Intramolecular N—H⋯O and O—H⋯O hydrogen bonds help to stabilize the molecular conformations. In the crystal structure, molecules are linked into one-dimensional chains parallel to the c axis by intermolecular O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960698/ /pubmed/21201804 http://dx.doi.org/10.1107/S1600536808026962 Text en © Xiao-Yang Qiu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Qiu, Xiao-Yang 2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide |
title | 2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide |
title_full | 2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide |
title_fullStr | 2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide |
title_full_unstemmed | 2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide |
title_short | 2-Hydroxy-N′-(2-methoxynaphthylidene)benzohydrazide |
title_sort | 2-hydroxy-n′-(2-methoxynaphthylidene)benzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960698/ https://www.ncbi.nlm.nih.gov/pubmed/21201804 http://dx.doi.org/10.1107/S1600536808026962 |
work_keys_str_mv | AT qiuxiaoyang 2hydroxyn2methoxynaphthylidenebenzohydrazide |