Cargando…
N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine
The molecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-molecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring....
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960703/ https://www.ncbi.nlm.nih.gov/pubmed/21201782 http://dx.doi.org/10.1107/S1600536808026652 |
Sumario: | The molecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-molecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. The dihedral angle between the two benzene rings is 69.52 (5)°. The methoxy group is coplanar with the benzene ring, as indicated by the C—O—C—C torsion angle of −179.56 (8)°. In the unit cell, molecules are linked together by intermolecular C—H⋯O hydrogen bonds, forming chains along the a axis; these chains are further stacked down the b axis by both intermolecular C—H⋯O and C—H⋯π interactions. |
---|