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N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine

The mol­ecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-mol­ecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring....

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Mirkhani, Valiollah, Vartooni, Akbar Rostami
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960703/
https://www.ncbi.nlm.nih.gov/pubmed/21201782
http://dx.doi.org/10.1107/S1600536808026652
Descripción
Sumario:The mol­ecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-mol­ecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. The dihedral angle between the two benzene rings is 69.52 (5)°. The meth­oxy group is coplanar with the benzene ring, as indicated by the C—O—C—C torsion angle of −179.56 (8)°. In the unit cell, mol­ecules are linked together by inter­molecular C—H⋯O hydrogen bonds, forming chains along the a axis; these chains are further stacked down the b axis by both inter­molecular C—H⋯O and C—H⋯π inter­actions.