Cargando…
N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine
The molecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-molecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring....
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960703/ https://www.ncbi.nlm.nih.gov/pubmed/21201782 http://dx.doi.org/10.1107/S1600536808026652 |
_version_ | 1782188804151443456 |
---|---|
author | Fun, Hoong-Kun Mirkhani, Valiollah Vartooni, Akbar Rostami |
author_facet | Fun, Hoong-Kun Mirkhani, Valiollah Vartooni, Akbar Rostami |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The molecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-molecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. The dihedral angle between the two benzene rings is 69.52 (5)°. The methoxy group is coplanar with the benzene ring, as indicated by the C—O—C—C torsion angle of −179.56 (8)°. In the unit cell, molecules are linked together by intermolecular C—H⋯O hydrogen bonds, forming chains along the a axis; these chains are further stacked down the b axis by both intermolecular C—H⋯O and C—H⋯π interactions. |
format | Text |
id | pubmed-2960703 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607032010-12-30 N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine Fun, Hoong-Kun Mirkhani, Valiollah Vartooni, Akbar Rostami Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-molecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. The dihedral angle between the two benzene rings is 69.52 (5)°. The methoxy group is coplanar with the benzene ring, as indicated by the C—O—C—C torsion angle of −179.56 (8)°. In the unit cell, molecules are linked together by intermolecular C—H⋯O hydrogen bonds, forming chains along the a axis; these chains are further stacked down the b axis by both intermolecular C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960703/ /pubmed/21201782 http://dx.doi.org/10.1107/S1600536808026652 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Mirkhani, Valiollah Vartooni, Akbar Rostami N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine |
title |
N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine |
title_full |
N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine |
title_fullStr |
N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine |
title_full_unstemmed |
N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine |
title_short |
N,N′-Bis(3-methoxybenzylidene)ethane-1,2-diamine |
title_sort | n,n′-bis(3-methoxybenzylidene)ethane-1,2-diamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960703/ https://www.ncbi.nlm.nih.gov/pubmed/21201782 http://dx.doi.org/10.1107/S1600536808026652 |
work_keys_str_mv | AT funhoongkun nnbis3methoxybenzylideneethane12diamine AT mirkhanivaliollah nnbis3methoxybenzylideneethane12diamine AT vartooniakbarrostami nnbis3methoxybenzylideneethane12diamine |