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N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine

The mol­ecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-mol­ecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring....

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Mirkhani, Valiollah, Vartooni, Akbar Rostami
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960703/
https://www.ncbi.nlm.nih.gov/pubmed/21201782
http://dx.doi.org/10.1107/S1600536808026652
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author Fun, Hoong-Kun
Mirkhani, Valiollah
Vartooni, Akbar Rostami
author_facet Fun, Hoong-Kun
Mirkhani, Valiollah
Vartooni, Akbar Rostami
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-mol­ecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. The dihedral angle between the two benzene rings is 69.52 (5)°. The meth­oxy group is coplanar with the benzene ring, as indicated by the C—O—C—C torsion angle of −179.56 (8)°. In the unit cell, mol­ecules are linked together by inter­molecular C—H⋯O hydrogen bonds, forming chains along the a axis; these chains are further stacked down the b axis by both inter­molecular C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-29607032010-12-30 N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine Fun, Hoong-Kun Mirkhani, Valiollah Vartooni, Akbar Rostami Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-mol­ecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. The dihedral angle between the two benzene rings is 69.52 (5)°. The meth­oxy group is coplanar with the benzene ring, as indicated by the C—O—C—C torsion angle of −179.56 (8)°. In the unit cell, mol­ecules are linked together by inter­molecular C—H⋯O hydrogen bonds, forming chains along the a axis; these chains are further stacked down the b axis by both inter­molecular C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960703/ /pubmed/21201782 http://dx.doi.org/10.1107/S1600536808026652 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Mirkhani, Valiollah
Vartooni, Akbar Rostami
N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine
title N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine
title_full N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine
title_fullStr N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine
title_full_unstemmed N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine
title_short N,N′-Bis(3-methoxy­benzyl­idene)ethane-1,2-diamine
title_sort n,n′-bis(3-methoxy­benzyl­idene)ethane-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960703/
https://www.ncbi.nlm.nih.gov/pubmed/21201782
http://dx.doi.org/10.1107/S1600536808026652
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