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Quinazoline-2,4(1H,3H)-dione
In the title compound, C(8)H(6)N(2)O(2), intermolecular N—H⋯O hydrogen bonds involving the amine and carbonyl groups create centrosymmetric dimers between adjacent nearly coplanar molecules. These dimers are further connected by weak N—H⋯O hydrogen bonds, forming a two-dimensional network. Molecu...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960707/ https://www.ncbi.nlm.nih.gov/pubmed/21201667 http://dx.doi.org/10.1107/S1600536808024240 |
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author | Liu, Ge |
author_facet | Liu, Ge |
author_sort | Liu, Ge |
collection | PubMed |
description | In the title compound, C(8)H(6)N(2)O(2), intermolecular N—H⋯O hydrogen bonds involving the amine and carbonyl groups create centrosymmetric dimers between adjacent nearly coplanar molecules. These dimers are further connected by weak N—H⋯O hydrogen bonds, forming a two-dimensional network. Molecules are packed in the crystal structure with adjacent benzene and pyrimidine rings approximately coplanar; the centroid–centroid separation is 3.863 Å and the dihedral angle between the mean planes is 0.64°, indicating the presence of weak intermolecular face-to-face π–π stacking interactions. |
format | Text |
id | pubmed-2960707 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607072010-12-30 Quinazoline-2,4(1H,3H)-dione Liu, Ge Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(6)N(2)O(2), intermolecular N—H⋯O hydrogen bonds involving the amine and carbonyl groups create centrosymmetric dimers between adjacent nearly coplanar molecules. These dimers are further connected by weak N—H⋯O hydrogen bonds, forming a two-dimensional network. Molecules are packed in the crystal structure with adjacent benzene and pyrimidine rings approximately coplanar; the centroid–centroid separation is 3.863 Å and the dihedral angle between the mean planes is 0.64°, indicating the presence of weak intermolecular face-to-face π–π stacking interactions. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960707/ /pubmed/21201667 http://dx.doi.org/10.1107/S1600536808024240 Text en © Ge Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Liu, Ge Quinazoline-2,4(1H,3H)-dione |
title | Quinazoline-2,4(1H,3H)-dione |
title_full | Quinazoline-2,4(1H,3H)-dione |
title_fullStr | Quinazoline-2,4(1H,3H)-dione |
title_full_unstemmed | Quinazoline-2,4(1H,3H)-dione |
title_short | Quinazoline-2,4(1H,3H)-dione |
title_sort | quinazoline-2,4(1h,3h)-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960707/ https://www.ncbi.nlm.nih.gov/pubmed/21201667 http://dx.doi.org/10.1107/S1600536808024240 |
work_keys_str_mv | AT liuge quinazoline241h3hdione |