4-[(3-Formyl-4-hydroxy­phen­yl)diazen­yl]-N-(pyrimidin-2-yl)benzene­sulfonamide

The title mol­ecule, C(17)H(13)N(5)O(4)S, has a trans configuration with respect to the diazenyl (azo) group. The pyrimidine ring and the terminal benzene ring are inclined at angles of 89.38 (4) and 1.6 (6)°, respectively, with respect to the central benzene ring. The conformation of the mol­ecule...

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Detalles Bibliográficos
Autores principales: El-Ghamry, Hoda, Issa, Raafat, El-Baradie, Kamal, Isagai, Keiko, Masaoka, Shigeyuki, Sakai, Ken
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960714/
https://www.ncbi.nlm.nih.gov/pubmed/21201664
http://dx.doi.org/10.1107/S1600536808024239
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author El-Ghamry, Hoda
Issa, Raafat
El-Baradie, Kamal
Isagai, Keiko
Masaoka, Shigeyuki
Sakai, Ken
author_facet El-Ghamry, Hoda
Issa, Raafat
El-Baradie, Kamal
Isagai, Keiko
Masaoka, Shigeyuki
Sakai, Ken
author_sort El-Ghamry, Hoda
collection PubMed
description The title mol­ecule, C(17)H(13)N(5)O(4)S, has a trans configuration with respect to the diazenyl (azo) group. The pyrimidine ring and the terminal benzene ring are inclined at angles of 89.38 (4) and 1.6 (6)°, respectively, with respect to the central benzene ring. The conformation of the mol­ecule is in part stabilized by an intra­molecular O—H⋯O hydrogen bond. In the crystal structure, mol­ecules related through inversion centers form hydrogen-bonded dimers involving the sulfon­amide N—H group and the N atom of the pyrimidine ring.
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spelling pubmed-29607142010-12-30 4-[(3-Formyl-4-hydroxy­phen­yl)diazen­yl]-N-(pyrimidin-2-yl)benzene­sulfonamide El-Ghamry, Hoda Issa, Raafat El-Baradie, Kamal Isagai, Keiko Masaoka, Shigeyuki Sakai, Ken Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(17)H(13)N(5)O(4)S, has a trans configuration with respect to the diazenyl (azo) group. The pyrimidine ring and the terminal benzene ring are inclined at angles of 89.38 (4) and 1.6 (6)°, respectively, with respect to the central benzene ring. The conformation of the mol­ecule is in part stabilized by an intra­molecular O—H⋯O hydrogen bond. In the crystal structure, mol­ecules related through inversion centers form hydrogen-bonded dimers involving the sulfon­amide N—H group and the N atom of the pyrimidine ring. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960714/ /pubmed/21201664 http://dx.doi.org/10.1107/S1600536808024239 Text en © El-Ghamry et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
El-Ghamry, Hoda
Issa, Raafat
El-Baradie, Kamal
Isagai, Keiko
Masaoka, Shigeyuki
Sakai, Ken
4-[(3-Formyl-4-hydroxy­phen­yl)diazen­yl]-N-(pyrimidin-2-yl)benzene­sulfonamide
title 4-[(3-Formyl-4-hydroxy­phen­yl)diazen­yl]-N-(pyrimidin-2-yl)benzene­sulfonamide
title_full 4-[(3-Formyl-4-hydroxy­phen­yl)diazen­yl]-N-(pyrimidin-2-yl)benzene­sulfonamide
title_fullStr 4-[(3-Formyl-4-hydroxy­phen­yl)diazen­yl]-N-(pyrimidin-2-yl)benzene­sulfonamide
title_full_unstemmed 4-[(3-Formyl-4-hydroxy­phen­yl)diazen­yl]-N-(pyrimidin-2-yl)benzene­sulfonamide
title_short 4-[(3-Formyl-4-hydroxy­phen­yl)diazen­yl]-N-(pyrimidin-2-yl)benzene­sulfonamide
title_sort 4-[(3-formyl-4-hydroxy­phen­yl)diazen­yl]-n-(pyrimidin-2-yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960714/
https://www.ncbi.nlm.nih.gov/pubmed/21201664
http://dx.doi.org/10.1107/S1600536808024239
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