catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1) O (2):O (3)]

In the title compound, [Co(C(6)H(2)N(2)O(4))(C(14)H(8)N(4))(H(2)O)](n), the Co atom is bonded to one N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (Pyphen) ligand, one N,O-bidentate pyrazine-2,3-dicarboxyl­ate (PZDC) dianion and one water mol­ecule in a distorted octa­hedral mer-CoN(3)O(3) geom...

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Detalles Bibliográficos
Autores principales: Xu, Zhan-Lin, Li, Xiu-Ying, Che, Guang-Bo, Lu, Lu, Xu, Chun-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960716/
https://www.ncbi.nlm.nih.gov/pubmed/21201648
http://dx.doi.org/10.1107/S1600536808027177
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author Xu, Zhan-Lin
Li, Xiu-Ying
Che, Guang-Bo
Lu, Lu
Xu, Chun-Hui
author_facet Xu, Zhan-Lin
Li, Xiu-Ying
Che, Guang-Bo
Lu, Lu
Xu, Chun-Hui
author_sort Xu, Zhan-Lin
collection PubMed
description In the title compound, [Co(C(6)H(2)N(2)O(4))(C(14)H(8)N(4))(H(2)O)](n), the Co atom is bonded to one N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (Pyphen) ligand, one N,O-bidentate pyrazine-2,3-dicarboxyl­ate (PZDC) dianion and one water mol­ecule in a distorted octa­hedral mer-CoN(3)O(3) geometry. The Co(II) atoms are bridged by the PZDC dianions, forming an infinite one-dimensional chain running along the b axis. Adjacent chains pack together through π–π stacking inter­actions [centroid–centroid separations = 3.498 (4) and 3.528 (4) Å], and O—H⋯O and O—H⋯N hydrogen bonds involving the water mol­ecule complete the structure.
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spelling pubmed-29607162010-12-30 catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1) O (2):O (3)] Xu, Zhan-Lin Li, Xiu-Ying Che, Guang-Bo Lu, Lu Xu, Chun-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(6)H(2)N(2)O(4))(C(14)H(8)N(4))(H(2)O)](n), the Co atom is bonded to one N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (Pyphen) ligand, one N,O-bidentate pyrazine-2,3-dicarboxyl­ate (PZDC) dianion and one water mol­ecule in a distorted octa­hedral mer-CoN(3)O(3) geometry. The Co(II) atoms are bridged by the PZDC dianions, forming an infinite one-dimensional chain running along the b axis. Adjacent chains pack together through π–π stacking inter­actions [centroid–centroid separations = 3.498 (4) and 3.528 (4) Å], and O—H⋯O and O—H⋯N hydrogen bonds involving the water mol­ecule complete the structure. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960716/ /pubmed/21201648 http://dx.doi.org/10.1107/S1600536808027177 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Zhan-Lin
Li, Xiu-Ying
Che, Guang-Bo
Lu, Lu
Xu, Chun-Hui
catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1) O (2):O (3)]
title catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1) O (2):O (3)]
title_full catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1) O (2):O (3)]
title_fullStr catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1) O (2):O (3)]
title_full_unstemmed catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1) O (2):O (3)]
title_short catena-Poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))cobalt(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1) O (2):O (3)]
title_sort catena-poly[[aqua­(pyrazino[2,3-f][1,10]phenanthroline-κ(2) n (8),n (9))cobalt(ii)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) n (1) o (2):o (3)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960716/
https://www.ncbi.nlm.nih.gov/pubmed/21201648
http://dx.doi.org/10.1107/S1600536808027177
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