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6,6′-Dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol
The molecule of the title compound, C(17)H(18)N(2)O(6), adopts a V-shaped conformation, the dihedral angle between the two halves of the molecule being 81.31 (4) °. There is one half-molecule in the asymmetric unit, with a crystallographic twofold rotation axis passing through the central C atom....
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960728/ https://www.ncbi.nlm.nih.gov/pubmed/21201787 http://dx.doi.org/10.1107/S1600536808026731 |
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author | Dong, Wen-Kui He, Xue-Ni Guan, Yong-Hong Xu, Li Ren, Zong-Li |
author_facet | Dong, Wen-Kui He, Xue-Ni Guan, Yong-Hong Xu, Li Ren, Zong-Li |
author_sort | Dong, Wen-Kui |
collection | PubMed |
description | The molecule of the title compound, C(17)H(18)N(2)O(6), adopts a V-shaped conformation, the dihedral angle between the two halves of the molecule being 81.31 (4) °. There is one half-molecule in the asymmetric unit, with a crystallographic twofold rotation axis passing through the central C atom. There are strong intramolecular O—H⋯N and O—H⋯O hydrogen bonds involving the hydroxy group and adjacent O and N atoms. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the molecules, forming an infinite three-dimensional supramolecular structure. |
format | Text |
id | pubmed-2960728 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607282010-12-30 6,6′-Dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol Dong, Wen-Kui He, Xue-Ni Guan, Yong-Hong Xu, Li Ren, Zong-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(17)H(18)N(2)O(6), adopts a V-shaped conformation, the dihedral angle between the two halves of the molecule being 81.31 (4) °. There is one half-molecule in the asymmetric unit, with a crystallographic twofold rotation axis passing through the central C atom. There are strong intramolecular O—H⋯N and O—H⋯O hydrogen bonds involving the hydroxy group and adjacent O and N atoms. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the molecules, forming an infinite three-dimensional supramolecular structure. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960728/ /pubmed/21201787 http://dx.doi.org/10.1107/S1600536808026731 Text en © Dong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Dong, Wen-Kui He, Xue-Ni Guan, Yong-Hong Xu, Li Ren, Zong-Li 6,6′-Dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title | 6,6′-Dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_full | 6,6′-Dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_fullStr | 6,6′-Dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_full_unstemmed | 6,6′-Dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_short | 6,6′-Dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_sort | 6,6′-dihydroxy-2,2′-[(propane-1,3-diyldioxy)bis(nitrilomethylidyne)]diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960728/ https://www.ncbi.nlm.nih.gov/pubmed/21201787 http://dx.doi.org/10.1107/S1600536808026731 |
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