Cargando…

6,6′-Dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol

The mol­ecule of the title compound, C(17)H(18)N(2)O(6), adopts a V-shaped conformation, the dihedral angle between the two halves of the mol­ecule being 81.31 (4) °. There is one half-mol­ecule in the asymmetric unit, with a crystallographic twofold rotation axis passing through the central C atom....

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Wen-Kui, He, Xue-Ni, Guan, Yong-Hong, Xu, Li, Ren, Zong-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960728/
https://www.ncbi.nlm.nih.gov/pubmed/21201787
http://dx.doi.org/10.1107/S1600536808026731
_version_ 1782188810110500864
author Dong, Wen-Kui
He, Xue-Ni
Guan, Yong-Hong
Xu, Li
Ren, Zong-Li
author_facet Dong, Wen-Kui
He, Xue-Ni
Guan, Yong-Hong
Xu, Li
Ren, Zong-Li
author_sort Dong, Wen-Kui
collection PubMed
description The mol­ecule of the title compound, C(17)H(18)N(2)O(6), adopts a V-shaped conformation, the dihedral angle between the two halves of the mol­ecule being 81.31 (4) °. There is one half-mol­ecule in the asymmetric unit, with a crystallographic twofold rotation axis passing through the central C atom. There are strong intra­molecular O—H⋯N and O—H⋯O hydrogen bonds involving the hydr­oxy group and adjacent O and N atoms. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules, forming an infinite three-dimensional supra­molecular structure.
format Text
id pubmed-2960728
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29607282010-12-30 6,6′-Dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol Dong, Wen-Kui He, Xue-Ni Guan, Yong-Hong Xu, Li Ren, Zong-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(17)H(18)N(2)O(6), adopts a V-shaped conformation, the dihedral angle between the two halves of the mol­ecule being 81.31 (4) °. There is one half-mol­ecule in the asymmetric unit, with a crystallographic twofold rotation axis passing through the central C atom. There are strong intra­molecular O—H⋯N and O—H⋯O hydrogen bonds involving the hydr­oxy group and adjacent O and N atoms. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules, forming an infinite three-dimensional supra­molecular structure. International Union of Crystallography 2008-08-23 /pmc/articles/PMC2960728/ /pubmed/21201787 http://dx.doi.org/10.1107/S1600536808026731 Text en © Dong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dong, Wen-Kui
He, Xue-Ni
Guan, Yong-Hong
Xu, Li
Ren, Zong-Li
6,6′-Dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title 6,6′-Dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_full 6,6′-Dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_fullStr 6,6′-Dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_full_unstemmed 6,6′-Dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_short 6,6′-Dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_sort 6,6′-dihydr­oxy-2,2′-[(propane-1,3-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960728/
https://www.ncbi.nlm.nih.gov/pubmed/21201787
http://dx.doi.org/10.1107/S1600536808026731
work_keys_str_mv AT dongwenkui 66dihydroxy22propane13diyldioxybisnitrilomethylidynediphenol
AT hexueni 66dihydroxy22propane13diyldioxybisnitrilomethylidynediphenol
AT guanyonghong 66dihydroxy22propane13diyldioxybisnitrilomethylidynediphenol
AT xuli 66dihydroxy22propane13diyldioxybisnitrilomethylidynediphenol
AT renzongli 66dihydroxy22propane13diyldioxybisnitrilomethylidynediphenol