catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′]

In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol­ecules are linked into a polymeric chain by bridging nitrate anions, for...

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Detalles Bibliográficos
Autores principales: Wang, Suwen, Li, Zhongfang, Wang, Xutao, Yu, Xianjin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960731/
https://www.ncbi.nlm.nih.gov/pubmed/21201632
http://dx.doi.org/10.1107/S1600536808021880
Descripción
Sumario:In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol­ecules are linked into a polymeric chain by bridging nitrate anions, forming axial Cu—O bonds of 2.535 (6) and 2.676 (7) Å, completing a distorted octa­hedral coordination geometry. The NH groups of the ligand form hydrogen bonds to the nitrate anions.

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