catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′]

In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol­ecules are linked into a polymeric chain by bridging nitrate anions, for...

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Detalles Bibliográficos
Autores principales: Wang, Suwen, Li, Zhongfang, Wang, Xutao, Yu, Xianjin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960731/
https://www.ncbi.nlm.nih.gov/pubmed/21201632
http://dx.doi.org/10.1107/S1600536808021880
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author Wang, Suwen
Li, Zhongfang
Wang, Xutao
Yu, Xianjin
author_facet Wang, Suwen
Li, Zhongfang
Wang, Xutao
Yu, Xianjin
author_sort Wang, Suwen
collection PubMed
description In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol­ecules are linked into a polymeric chain by bridging nitrate anions, forming axial Cu—O bonds of 2.535 (6) and 2.676 (7) Å, completing a distorted octa­hedral coordination geometry. The NH groups of the ligand form hydrogen bonds to the nitrate anions.
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spelling pubmed-29607312010-12-30 catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′] Wang, Suwen Li, Zhongfang Wang, Xutao Yu, Xianjin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol­ecules are linked into a polymeric chain by bridging nitrate anions, forming axial Cu—O bonds of 2.535 (6) and 2.676 (7) Å, completing a distorted octa­hedral coordination geometry. The NH groups of the ligand form hydrogen bonds to the nitrate anions. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2960731/ /pubmed/21201632 http://dx.doi.org/10.1107/S1600536808021880 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Suwen
Li, Zhongfang
Wang, Xutao
Yu, Xianjin
catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′]
title catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′]
title_full catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′]
title_fullStr catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′]
title_short catena-Poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) N,N′,N′′,O)copper(II)]-μ-nitrato-κ(2) O:O′]
title_sort catena-poly[[(2-{1-[2-(2-amino­ethyl­amino)ethyl­imino]­eth­yl}-5-methoxy­phenolato-κ(4) n,n′,n′′,o)copper(ii)]-μ-nitrato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960731/
https://www.ncbi.nlm.nih.gov/pubmed/21201632
http://dx.doi.org/10.1107/S1600536808021880
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