(E)-Methyl N′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate

The mol­ecule of the title compound, C(11)H(14)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate plane is 12.06 (9)°. Mol­ecules are linked into a one-dimensional network by N—H⋯O hydrogen bonds and C—H⋯π in...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Wei-Ping, Yu, Wen-Bo, Zhou, Xue-Feng, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960734/
https://www.ncbi.nlm.nih.gov/pubmed/21201666
http://dx.doi.org/10.1107/S1600536808024264
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author Lv, Lu-Ping
Yu, Wei-Ping
Yu, Wen-Bo
Zhou, Xue-Feng
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Wei-Ping
Yu, Wen-Bo
Zhou, Xue-Feng
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The mol­ecule of the title compound, C(11)H(14)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate plane is 12.06 (9)°. Mol­ecules are linked into a one-dimensional network by N—H⋯O hydrogen bonds and C—H⋯π inter­actions. The benzene rings of inversion-related mol­ecules are stacked with their centroids separated by 3.777 (1) Å, indicating π–π inter­actions.
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spelling pubmed-29607342010-12-30 (E)-Methyl N′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate Lv, Lu-Ping Yu, Wei-Ping Yu, Wen-Bo Zhou, Xue-Feng Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(11)H(14)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate plane is 12.06 (9)°. Mol­ecules are linked into a one-dimensional network by N—H⋯O hydrogen bonds and C—H⋯π inter­actions. The benzene rings of inversion-related mol­ecules are stacked with their centroids separated by 3.777 (1) Å, indicating π–π inter­actions. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960734/ /pubmed/21201666 http://dx.doi.org/10.1107/S1600536808024264 Text en © Lv et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Wei-Ping
Yu, Wen-Bo
Zhou, Xue-Feng
Hu, Xian-Chao
(E)-Methyl N′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title (E)-Methyl N′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_full (E)-Methyl N′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_fullStr (E)-Methyl N′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_full_unstemmed (E)-Methyl N′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_short (E)-Methyl N′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_sort (e)-methyl n′-[1-(4-methoxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960734/
https://www.ncbi.nlm.nih.gov/pubmed/21201666
http://dx.doi.org/10.1107/S1600536808024264
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