(E)-Methyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate

The mol­ecule of the title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate plane is 8.98 (7)°. Intra­molecular O—H⋯N and C—H⋯N hydrogen bonds are observed. Mol­ecules are linked into ch...

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Detalles Bibliográficos
Autores principales: Zhu, Bin, Cheng, Xiang-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960736/
https://www.ncbi.nlm.nih.gov/pubmed/21201730
http://dx.doi.org/10.1107/S1600536808024434
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author Zhu, Bin
Cheng, Xiang-Wei
author_facet Zhu, Bin
Cheng, Xiang-Wei
author_sort Zhu, Bin
collection PubMed
description The mol­ecule of the title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate plane is 8.98 (7)°. Intra­molecular O—H⋯N and C—H⋯N hydrogen bonds are observed. Mol­ecules are linked into chains along the c axis by N—H⋯O hydrogen bonds. In addition, C—H⋯π inter­actions are observed.
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spelling pubmed-29607362010-12-30 (E)-Methyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate Zhu, Bin Cheng, Xiang-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl­ate plane is 8.98 (7)°. Intra­molecular O—H⋯N and C—H⋯N hydrogen bonds are observed. Mol­ecules are linked into chains along the c axis by N—H⋯O hydrogen bonds. In addition, C—H⋯π inter­actions are observed. International Union of Crystallography 2008-08-13 /pmc/articles/PMC2960736/ /pubmed/21201730 http://dx.doi.org/10.1107/S1600536808024434 Text en © Zhu and Cheng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Bin
Cheng, Xiang-Wei
(E)-Methyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title (E)-Methyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_full (E)-Methyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_fullStr (E)-Methyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_full_unstemmed (E)-Methyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_short (E)-Methyl N′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
title_sort (e)-methyl n′-[1-(2-hydroxy­phen­yl)ethyl­idene]hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960736/
https://www.ncbi.nlm.nih.gov/pubmed/21201730
http://dx.doi.org/10.1107/S1600536808024434
work_keys_str_mv AT zhubin emethyln12hydroxyphenylethylidenehydrazinecarboxylate
AT chengxiangwei emethyln12hydroxyphenylethylidenehydrazinecarboxylate

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