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Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate
The title compound {systematic name: bis[1,4(η(5))-cyclopentadienyl]hexakis(μ-diethyl phosphito)-1:2κ(6) P:O;3:4κ(6) O:P-μ-oxalato-2:3κ(4) O (1),O (2):O (1′),O (2′)-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-br...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960739/ https://www.ncbi.nlm.nih.gov/pubmed/21201588 http://dx.doi.org/10.1107/S1600536808024458 |
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author | McLauchlan, Craig C. Anderson, Alexander E. |
author_facet | McLauchlan, Craig C. Anderson, Alexander E. |
author_sort | McLauchlan, Craig C. |
collection | PubMed |
description | The title compound {systematic name: bis[1,4(η(5))-cyclopentadienyl]hexakis(μ-diethyl phosphito)-1:2κ(6) P:O;3:4κ(6) O:P-μ-oxalato-2:3κ(4) O (1),O (2):O (1′),O (2′)-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclopentadienyl ring. The unique V atom has six O atom neighbors in an approximately octahedral arrangement; the V—O bond trans to the V=O bond is significantly lengthened. |
format | Text |
id | pubmed-2960739 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607392010-12-30 Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate McLauchlan, Craig C. Anderson, Alexander E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound {systematic name: bis[1,4(η(5))-cyclopentadienyl]hexakis(μ-diethyl phosphito)-1:2κ(6) P:O;3:4κ(6) O:P-μ-oxalato-2:3κ(4) O (1),O (2):O (1′),O (2′)-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclopentadienyl ring. The unique V atom has six O atom neighbors in an approximately octahedral arrangement; the V—O bond trans to the V=O bond is significantly lengthened. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960739/ /pubmed/21201588 http://dx.doi.org/10.1107/S1600536808024458 Text en © McLauchlan and Anderson 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers McLauchlan, Craig C. Anderson, Alexander E. Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate |
title | Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3)
P,P′,P′′)cobaltate(III)-κ(3)
O,O′,O′′]oxovanadium(IV)}-μ-oxalate |
title_full | Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3)
P,P′,P′′)cobaltate(III)-κ(3)
O,O′,O′′]oxovanadium(IV)}-μ-oxalate |
title_fullStr | Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3)
P,P′,P′′)cobaltate(III)-κ(3)
O,O′,O′′]oxovanadium(IV)}-μ-oxalate |
title_full_unstemmed | Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3)
P,P′,P′′)cobaltate(III)-κ(3)
O,O′,O′′]oxovanadium(IV)}-μ-oxalate |
title_short | Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3)
P,P′,P′′)cobaltate(III)-κ(3)
O,O′,O′′]oxovanadium(IV)}-μ-oxalate |
title_sort | bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3)
p,p′,p′′)cobaltate(iii)-κ(3)
o,o′,o′′]oxovanadium(iv)}-μ-oxalate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960739/ https://www.ncbi.nlm.nih.gov/pubmed/21201588 http://dx.doi.org/10.1107/S1600536808024458 |
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