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Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate

The title compound {systematic name: bis[1,4(η(5))-cyclo­penta­dien­yl]hexa­kis(μ-diethyl phosphito)-1:2κ(6) P:O;3:4κ(6) O:P-μ-ox­alato-2:3κ(4) O (1),O (2):O (1′),O (2′)-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-br...

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Detalles Bibliográficos
Autores principales: McLauchlan, Craig C., Anderson, Alexander E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960739/
https://www.ncbi.nlm.nih.gov/pubmed/21201588
http://dx.doi.org/10.1107/S1600536808024458
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author McLauchlan, Craig C.
Anderson, Alexander E.
author_facet McLauchlan, Craig C.
Anderson, Alexander E.
author_sort McLauchlan, Craig C.
collection PubMed
description The title compound {systematic name: bis[1,4(η(5))-cyclo­penta­dien­yl]hexa­kis(μ-diethyl phosphito)-1:2κ(6) P:O;3:4κ(6) O:P-μ-ox­alato-2:3κ(4) O (1),O (2):O (1′),O (2′)-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclo­penta­dienyl ring. The unique V atom has six O atom neighbors in an approximately octa­hedral arrangement; the V—O bond trans to the V=O bond is significantly lengthened.
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spelling pubmed-29607392010-12-30 Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate McLauchlan, Craig C. Anderson, Alexander E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound {systematic name: bis[1,4(η(5))-cyclo­penta­dien­yl]hexa­kis(μ-diethyl phosphito)-1:2κ(6) P:O;3:4κ(6) O:P-μ-ox­alato-2:3κ(4) O (1),O (2):O (1′),O (2′)-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclo­penta­dienyl ring. The unique V atom has six O atom neighbors in an approximately octa­hedral arrangement; the V—O bond trans to the V=O bond is significantly lengthened. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960739/ /pubmed/21201588 http://dx.doi.org/10.1107/S1600536808024458 Text en © McLauchlan and Anderson 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
McLauchlan, Craig C.
Anderson, Alexander E.
Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_full Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_fullStr Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_full_unstemmed Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_short Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_sort bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) p,p′,p′′)cobaltate(iii)-κ(3) o,o′,o′′]oxovanadium(iv)}-μ-oxalate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960739/
https://www.ncbi.nlm.nih.gov/pubmed/21201588
http://dx.doi.org/10.1107/S1600536808024458
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