Tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) N,O)technetate(I)

The asymmetric unit of the title compound, (C(8)H(20)N)[Tc(C(10)H(6)NO(2))Cl(CO)(3)], consists of two crystallographically independent technetium complexes related via a pseudo-inversion centre and two tetra­ethyl­ammonium cations. The Tc atoms have slightly distorted octa­hedral coordination geomet...

Descripción completa

Detalles Bibliográficos
Autores principales: Schmalle, Helmut W., Alberto, Roger
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960740/
https://www.ncbi.nlm.nih.gov/pubmed/21201647
http://dx.doi.org/10.1107/S160053680802713X
_version_ 1782188812920684544
author Schmalle, Helmut W.
Alberto, Roger
author_facet Schmalle, Helmut W.
Alberto, Roger
author_sort Schmalle, Helmut W.
collection PubMed
description The asymmetric unit of the title compound, (C(8)H(20)N)[Tc(C(10)H(6)NO(2))Cl(CO)(3)], consists of two crystallographically independent technetium complexes related via a pseudo-inversion centre and two tetra­ethyl­ammonium cations. The Tc atoms have slightly distorted octa­hedral coordination geometries, and they are linked with the cations by inter­molecular C—H⋯O and C—H⋯Cl hydrogen-bonding contacts, forming two-dimensional columns, which lie approximately parallel to (001) in the crystal structure. The isochinolate (isoquinoline-1-carboxyl­ate) ligands link the columns by partial π–π stacking [centroid–centroid distance 4.3733 (11) Å], forming a three-dimensional network structure.
format Text
id pubmed-2960740
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29607402010-12-30 Tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) N,O)technetate(I) Schmalle, Helmut W. Alberto, Roger Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(8)H(20)N)[Tc(C(10)H(6)NO(2))Cl(CO)(3)], consists of two crystallographically independent technetium complexes related via a pseudo-inversion centre and two tetra­ethyl­ammonium cations. The Tc atoms have slightly distorted octa­hedral coordination geometries, and they are linked with the cations by inter­molecular C—H⋯O and C—H⋯Cl hydrogen-bonding contacts, forming two-dimensional columns, which lie approximately parallel to (001) in the crystal structure. The isochinolate (isoquinoline-1-carboxyl­ate) ligands link the columns by partial π–π stacking [centroid–centroid distance 4.3733 (11) Å], forming a three-dimensional network structure. International Union of Crystallography 2008-08-30 /pmc/articles/PMC2960740/ /pubmed/21201647 http://dx.doi.org/10.1107/S160053680802713X Text en © Schmalle and Alberto 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schmalle, Helmut W.
Alberto, Roger
Tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) N,O)technetate(I)
title Tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) N,O)technetate(I)
title_full Tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) N,O)technetate(I)
title_fullStr Tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) N,O)technetate(I)
title_full_unstemmed Tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) N,O)technetate(I)
title_short Tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) N,O)technetate(I)
title_sort tetra­ethyl­ammonium tricarbonyl­chlorido(isoquinoline-1-carboxyl­ato-κ(2) n,o)technetate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960740/
https://www.ncbi.nlm.nih.gov/pubmed/21201647
http://dx.doi.org/10.1107/S160053680802713X
work_keys_str_mv AT schmallehelmutw tetraethylammoniumtricarbonylchloridoisoquinoline1carboxylatok2notechnetatei
AT albertoroger tetraethylammoniumtricarbonylchloridoisoquinoline1carboxylatok2notechnetatei

Ejemplares similares