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2-Methyl-3-(4-nitrophenyl)acrylic acid
The title compound, C(10)H(9)NO(4), forms R (2) (2)(8) dimers due to intermolecular O—H⋯O hydrogen bonding in the crystal structure. Two dimers are further linked to each other through two intermolecular C—H⋯O hydrogen bonds, forming an R (3) (3)(7) ring motif. The nitro groups form an intramolec...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960743/ https://www.ncbi.nlm.nih.gov/pubmed/21201703 http://dx.doi.org/10.1107/S1600536808024999 |
Sumario: | The title compound, C(10)H(9)NO(4), forms R (2) (2)(8) dimers due to intermolecular O—H⋯O hydrogen bonding in the crystal structure. Two dimers are further linked to each other through two intermolecular C—H⋯O hydrogen bonds, forming an R (3) (3)(7) ring motif. The nitro groups form an intramolecular C—H⋯O hydrogen bond mimicking a five-membered ring. As a result of these hydrogen bonds, polymeric sheets are formed. The aromatic ring makes a dihedral angle of 42.84 (8)° with the carboxylate group and an angle of 8.01 (14)° with the nitro group. There is a π-interaction (N—O⋯π) between the nitro group and the aromatic ring, with a distance of 3.7572 (14) Å between the N atom and the centroid of the aromatic ring. |
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