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2-Methyl-3-(4-nitro­phen­yl)acrylic acid

The title compound, C(10)H(9)NO(4), forms R (2) (2)(8) dimers due to inter­molecular O—H⋯O hydrogen bonding in the crystal structure. Two dimers are further linked to each other through two inter­molecular C—H⋯O hydrogen bonds, forming an R (3) (3)(7) ring motif. The nitro groups form an intra­molec...

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Detalles Bibliográficos
Autores principales: Muhammad, Niaz, Tahir, M. Nawaz, Zia-ur-Rehman, Ali, Saqib
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960743/
https://www.ncbi.nlm.nih.gov/pubmed/21201703
http://dx.doi.org/10.1107/S1600536808024999
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author Muhammad, Niaz
Tahir, M. Nawaz
Zia-ur-Rehman,
Ali, Saqib
author_facet Muhammad, Niaz
Tahir, M. Nawaz
Zia-ur-Rehman,
Ali, Saqib
author_sort Muhammad, Niaz
collection PubMed
description The title compound, C(10)H(9)NO(4), forms R (2) (2)(8) dimers due to inter­molecular O—H⋯O hydrogen bonding in the crystal structure. Two dimers are further linked to each other through two inter­molecular C—H⋯O hydrogen bonds, forming an R (3) (3)(7) ring motif. The nitro groups form an intra­molecular C—H⋯O hydrogen bond mimicking a five-membered ring. As a result of these hydrogen bonds, polymeric sheets are formed. The aromatic ring makes a dihedral angle of 42.84 (8)° with the carboxyl­ate group and an angle of 8.01 (14)° with the nitro group. There is a π-inter­action (N—O⋯π) between the nitro group and the aromatic ring, with a distance of 3.7572 (14) Å between the N atom and the centroid of the aromatic ring.
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spelling pubmed-29607432010-12-30 2-Methyl-3-(4-nitro­phen­yl)acrylic acid Muhammad, Niaz Tahir, M. Nawaz Zia-ur-Rehman, Ali, Saqib Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(9)NO(4), forms R (2) (2)(8) dimers due to inter­molecular O—H⋯O hydrogen bonding in the crystal structure. Two dimers are further linked to each other through two inter­molecular C—H⋯O hydrogen bonds, forming an R (3) (3)(7) ring motif. The nitro groups form an intra­molecular C—H⋯O hydrogen bond mimicking a five-membered ring. As a result of these hydrogen bonds, polymeric sheets are formed. The aromatic ring makes a dihedral angle of 42.84 (8)° with the carboxyl­ate group and an angle of 8.01 (14)° with the nitro group. There is a π-inter­action (N—O⋯π) between the nitro group and the aromatic ring, with a distance of 3.7572 (14) Å between the N atom and the centroid of the aromatic ring. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960743/ /pubmed/21201703 http://dx.doi.org/10.1107/S1600536808024999 Text en © Muhammad et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Muhammad, Niaz
Tahir, M. Nawaz
Zia-ur-Rehman,
Ali, Saqib
2-Methyl-3-(4-nitro­phen­yl)acrylic acid
title 2-Methyl-3-(4-nitro­phen­yl)acrylic acid
title_full 2-Methyl-3-(4-nitro­phen­yl)acrylic acid
title_fullStr 2-Methyl-3-(4-nitro­phen­yl)acrylic acid
title_full_unstemmed 2-Methyl-3-(4-nitro­phen­yl)acrylic acid
title_short 2-Methyl-3-(4-nitro­phen­yl)acrylic acid
title_sort 2-methyl-3-(4-nitro­phen­yl)acrylic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960743/
https://www.ncbi.nlm.nih.gov/pubmed/21201703
http://dx.doi.org/10.1107/S1600536808024999
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