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2-Methyl-3-(4-nitrophenyl)acrylic acid
The title compound, C(10)H(9)NO(4), forms R (2) (2)(8) dimers due to intermolecular O—H⋯O hydrogen bonding in the crystal structure. Two dimers are further linked to each other through two intermolecular C—H⋯O hydrogen bonds, forming an R (3) (3)(7) ring motif. The nitro groups form an intramolec...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960743/ https://www.ncbi.nlm.nih.gov/pubmed/21201703 http://dx.doi.org/10.1107/S1600536808024999 |
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author | Muhammad, Niaz Tahir, M. Nawaz Zia-ur-Rehman, Ali, Saqib |
author_facet | Muhammad, Niaz Tahir, M. Nawaz Zia-ur-Rehman, Ali, Saqib |
author_sort | Muhammad, Niaz |
collection | PubMed |
description | The title compound, C(10)H(9)NO(4), forms R (2) (2)(8) dimers due to intermolecular O—H⋯O hydrogen bonding in the crystal structure. Two dimers are further linked to each other through two intermolecular C—H⋯O hydrogen bonds, forming an R (3) (3)(7) ring motif. The nitro groups form an intramolecular C—H⋯O hydrogen bond mimicking a five-membered ring. As a result of these hydrogen bonds, polymeric sheets are formed. The aromatic ring makes a dihedral angle of 42.84 (8)° with the carboxylate group and an angle of 8.01 (14)° with the nitro group. There is a π-interaction (N—O⋯π) between the nitro group and the aromatic ring, with a distance of 3.7572 (14) Å between the N atom and the centroid of the aromatic ring. |
format | Text |
id | pubmed-2960743 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607432010-12-30 2-Methyl-3-(4-nitrophenyl)acrylic acid Muhammad, Niaz Tahir, M. Nawaz Zia-ur-Rehman, Ali, Saqib Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(9)NO(4), forms R (2) (2)(8) dimers due to intermolecular O—H⋯O hydrogen bonding in the crystal structure. Two dimers are further linked to each other through two intermolecular C—H⋯O hydrogen bonds, forming an R (3) (3)(7) ring motif. The nitro groups form an intramolecular C—H⋯O hydrogen bond mimicking a five-membered ring. As a result of these hydrogen bonds, polymeric sheets are formed. The aromatic ring makes a dihedral angle of 42.84 (8)° with the carboxylate group and an angle of 8.01 (14)° with the nitro group. There is a π-interaction (N—O⋯π) between the nitro group and the aromatic ring, with a distance of 3.7572 (14) Å between the N atom and the centroid of the aromatic ring. International Union of Crystallography 2008-08-06 /pmc/articles/PMC2960743/ /pubmed/21201703 http://dx.doi.org/10.1107/S1600536808024999 Text en © Muhammad et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Muhammad, Niaz Tahir, M. Nawaz Zia-ur-Rehman, Ali, Saqib 2-Methyl-3-(4-nitrophenyl)acrylic acid |
title | 2-Methyl-3-(4-nitrophenyl)acrylic acid |
title_full | 2-Methyl-3-(4-nitrophenyl)acrylic acid |
title_fullStr | 2-Methyl-3-(4-nitrophenyl)acrylic acid |
title_full_unstemmed | 2-Methyl-3-(4-nitrophenyl)acrylic acid |
title_short | 2-Methyl-3-(4-nitrophenyl)acrylic acid |
title_sort | 2-methyl-3-(4-nitrophenyl)acrylic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960743/ https://www.ncbi.nlm.nih.gov/pubmed/21201703 http://dx.doi.org/10.1107/S1600536808024999 |
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