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1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate

In the title compound, C(12)H(12)NS(+)·C(6)H(4)ClO(3)S(−), the cation is almost planar and exists in the E configuration. The cations and anions form alternate layers parallel to the ab plane. Within each layer, both cations and anions form chains directed along the b axis. The mol­ecules are inter­...

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Detalles Bibliográficos
Autores principales: Chantrapromma, Suchada, Laksana, Chotika, Ruanwas, Pumsak, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960744/
https://www.ncbi.nlm.nih.gov/pubmed/21201916
http://dx.doi.org/10.1107/S1600536808003929
Descripción
Sumario:In the title compound, C(12)H(12)NS(+)·C(6)H(4)ClO(3)S(−), the cation is almost planar and exists in the E configuration. The cations and anions form alternate layers parallel to the ab plane. Within each layer, both cations and anions form chains directed along the b axis. The mol­ecules are inter­connected by weak C—H⋯O inter­actions into a three-dimensional network. The crystal structure is further stabilized by C—H⋯π inter­actions involving the thio­phene ring. The sulfonate and thio­phene groups are involved in weak intra­molecular C—H⋯O and C—H⋯S inter­actions, respectively. The latter intra­molecular hydrogen bonds produce S(5) ring motifs.