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1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate

In the title compound, C(12)H(12)NS(+)·C(6)H(4)ClO(3)S(−), the cation is almost planar and exists in the E configuration. The cations and anions form alternate layers parallel to the ab plane. Within each layer, both cations and anions form chains directed along the b axis. The mol­ecules are inter­...

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Autores principales: Chantrapromma, Suchada, Laksana, Chotika, Ruanwas, Pumsak, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960744/
https://www.ncbi.nlm.nih.gov/pubmed/21201916
http://dx.doi.org/10.1107/S1600536808003929
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author Chantrapromma, Suchada
Laksana, Chotika
Ruanwas, Pumsak
Fun, Hoong-Kun
author_facet Chantrapromma, Suchada
Laksana, Chotika
Ruanwas, Pumsak
Fun, Hoong-Kun
author_sort Chantrapromma, Suchada
collection PubMed
description In the title compound, C(12)H(12)NS(+)·C(6)H(4)ClO(3)S(−), the cation is almost planar and exists in the E configuration. The cations and anions form alternate layers parallel to the ab plane. Within each layer, both cations and anions form chains directed along the b axis. The mol­ecules are inter­connected by weak C—H⋯O inter­actions into a three-dimensional network. The crystal structure is further stabilized by C—H⋯π inter­actions involving the thio­phene ring. The sulfonate and thio­phene groups are involved in weak intra­molecular C—H⋯O and C—H⋯S inter­actions, respectively. The latter intra­molecular hydrogen bonds produce S(5) ring motifs.
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spelling pubmed-29607442010-12-30 1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate Chantrapromma, Suchada Laksana, Chotika Ruanwas, Pumsak Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(12)NS(+)·C(6)H(4)ClO(3)S(−), the cation is almost planar and exists in the E configuration. The cations and anions form alternate layers parallel to the ab plane. Within each layer, both cations and anions form chains directed along the b axis. The mol­ecules are inter­connected by weak C—H⋯O inter­actions into a three-dimensional network. The crystal structure is further stabilized by C—H⋯π inter­actions involving the thio­phene ring. The sulfonate and thio­phene groups are involved in weak intra­molecular C—H⋯O and C—H⋯S inter­actions, respectively. The latter intra­molecular hydrogen bonds produce S(5) ring motifs. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960744/ /pubmed/21201916 http://dx.doi.org/10.1107/S1600536808003929 Text en © Chantrapromma et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chantrapromma, Suchada
Laksana, Chotika
Ruanwas, Pumsak
Fun, Hoong-Kun
1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate
title 1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate
title_full 1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate
title_fullStr 1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate
title_full_unstemmed 1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate
title_short 1-Methyl-4-[(E)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate
title_sort 1-methyl-4-[(e)-2-(2-thien­yl)ethen­yl]pyridinium 4-chloro­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960744/
https://www.ncbi.nlm.nih.gov/pubmed/21201916
http://dx.doi.org/10.1107/S1600536808003929
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AT ruanwaspumsak 1methyl4e22thienylethenylpyridinium4chlorobenzenesulfonate
AT funhoongkun 1methyl4e22thienylethenylpyridinium4chlorobenzenesulfonate