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1-Methyl-4-[(E)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate
In the title compound, C(12)H(12)NS(+)·C(6)H(4)ClO(3)S(−), the cation is almost planar and exists in the E configuration. The cations and anions form alternate layers parallel to the ab plane. Within each layer, both cations and anions form chains directed along the b axis. The molecules are inter...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960744/ https://www.ncbi.nlm.nih.gov/pubmed/21201916 http://dx.doi.org/10.1107/S1600536808003929 |
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author | Chantrapromma, Suchada Laksana, Chotika Ruanwas, Pumsak Fun, Hoong-Kun |
author_facet | Chantrapromma, Suchada Laksana, Chotika Ruanwas, Pumsak Fun, Hoong-Kun |
author_sort | Chantrapromma, Suchada |
collection | PubMed |
description | In the title compound, C(12)H(12)NS(+)·C(6)H(4)ClO(3)S(−), the cation is almost planar and exists in the E configuration. The cations and anions form alternate layers parallel to the ab plane. Within each layer, both cations and anions form chains directed along the b axis. The molecules are interconnected by weak C—H⋯O interactions into a three-dimensional network. The crystal structure is further stabilized by C—H⋯π interactions involving the thiophene ring. The sulfonate and thiophene groups are involved in weak intramolecular C—H⋯O and C—H⋯S interactions, respectively. The latter intramolecular hydrogen bonds produce S(5) ring motifs. |
format | Text |
id | pubmed-2960744 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607442010-12-30 1-Methyl-4-[(E)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate Chantrapromma, Suchada Laksana, Chotika Ruanwas, Pumsak Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(12)NS(+)·C(6)H(4)ClO(3)S(−), the cation is almost planar and exists in the E configuration. The cations and anions form alternate layers parallel to the ab plane. Within each layer, both cations and anions form chains directed along the b axis. The molecules are interconnected by weak C—H⋯O interactions into a three-dimensional network. The crystal structure is further stabilized by C—H⋯π interactions involving the thiophene ring. The sulfonate and thiophene groups are involved in weak intramolecular C—H⋯O and C—H⋯S interactions, respectively. The latter intramolecular hydrogen bonds produce S(5) ring motifs. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960744/ /pubmed/21201916 http://dx.doi.org/10.1107/S1600536808003929 Text en © Chantrapromma et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chantrapromma, Suchada Laksana, Chotika Ruanwas, Pumsak Fun, Hoong-Kun 1-Methyl-4-[(E)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate |
title | 1-Methyl-4-[(E)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate
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title_full | 1-Methyl-4-[(E)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate
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title_fullStr | 1-Methyl-4-[(E)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate
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title_full_unstemmed | 1-Methyl-4-[(E)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate
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title_short | 1-Methyl-4-[(E)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate
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title_sort | 1-methyl-4-[(e)-2-(2-thienyl)ethenyl]pyridinium 4-chlorobenzenesulfonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960744/ https://www.ncbi.nlm.nih.gov/pubmed/21201916 http://dx.doi.org/10.1107/S1600536808003929 |
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