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(Dicyanamido)[tris­(2-pyridylmeth­yl)amine]zinc(II) perchlorate

In the title complex, [Zn(C(2)N(3))(C(18)H(18)N(4))]ClO(4), the Zn(II) ion has a slightly distorted trigonal–bipyramidal ZnN(5) coordination geometry. The crystal structure is stabilized by weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds. In addition, there are relatively close contacts between...

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Detalles Bibliográficos
Autores principales: Li, Hong, Zhao, Hong Yan, Zhang, Shi Guo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960752/
https://www.ncbi.nlm.nih.gov/pubmed/21201877
http://dx.doi.org/10.1107/S1600536808004741
Descripción
Sumario:In the title complex, [Zn(C(2)N(3))(C(18)H(18)N(4))]ClO(4), the Zn(II) ion has a slightly distorted trigonal–bipyramidal ZnN(5) coordination geometry. The crystal structure is stabilized by weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds. In addition, there are relatively close contacts between the O atoms of the perchlorate anion and symmetry-related pyridine rings [O⋯Cg = 3.179 (3) and 3.236 (3) Å, where Cg is the centroid of a pyridine ring], and between the terminal N atom of the dicyanamide ligand and pyridine rings [N⋯Cg = 3.381 (4)–3.761 (3) Å]. The central N atom of the dicyanamide ligand is disordered over two sites in an approximately 0.6:0.4 ratio.