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(Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate
In the title complex, [Zn(C(2)N(3))(C(18)H(18)N(4))]ClO(4), the Zn(II) ion has a slightly distorted trigonal–bipyramidal ZnN(5) coordination geometry. The crystal structure is stabilized by weak intermolecular C—H⋯O and C—H⋯N hydrogen bonds. In addition, there are relatively close contacts between...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960752/ https://www.ncbi.nlm.nih.gov/pubmed/21201877 http://dx.doi.org/10.1107/S1600536808004741 |
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author | Li, Hong Zhao, Hong Yan Zhang, Shi Guo |
author_facet | Li, Hong Zhao, Hong Yan Zhang, Shi Guo |
author_sort | Li, Hong |
collection | PubMed |
description | In the title complex, [Zn(C(2)N(3))(C(18)H(18)N(4))]ClO(4), the Zn(II) ion has a slightly distorted trigonal–bipyramidal ZnN(5) coordination geometry. The crystal structure is stabilized by weak intermolecular C—H⋯O and C—H⋯N hydrogen bonds. In addition, there are relatively close contacts between the O atoms of the perchlorate anion and symmetry-related pyridine rings [O⋯Cg = 3.179 (3) and 3.236 (3) Å, where Cg is the centroid of a pyridine ring], and between the terminal N atom of the dicyanamide ligand and pyridine rings [N⋯Cg = 3.381 (4)–3.761 (3) Å]. The central N atom of the dicyanamide ligand is disordered over two sites in an approximately 0.6:0.4 ratio. |
format | Text |
id | pubmed-2960752 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607522010-12-30 (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate Li, Hong Zhao, Hong Yan Zhang, Shi Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(2)N(3))(C(18)H(18)N(4))]ClO(4), the Zn(II) ion has a slightly distorted trigonal–bipyramidal ZnN(5) coordination geometry. The crystal structure is stabilized by weak intermolecular C—H⋯O and C—H⋯N hydrogen bonds. In addition, there are relatively close contacts between the O atoms of the perchlorate anion and symmetry-related pyridine rings [O⋯Cg = 3.179 (3) and 3.236 (3) Å, where Cg is the centroid of a pyridine ring], and between the terminal N atom of the dicyanamide ligand and pyridine rings [N⋯Cg = 3.381 (4)–3.761 (3) Å]. The central N atom of the dicyanamide ligand is disordered over two sites in an approximately 0.6:0.4 ratio. International Union of Crystallography 2008-02-27 /pmc/articles/PMC2960752/ /pubmed/21201877 http://dx.doi.org/10.1107/S1600536808004741 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Hong Zhao, Hong Yan Zhang, Shi Guo (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate |
title | (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate |
title_full | (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate |
title_fullStr | (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate |
title_full_unstemmed | (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate |
title_short | (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate |
title_sort | (dicyanamido)[tris(2-pyridylmethyl)amine]zinc(ii) perchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960752/ https://www.ncbi.nlm.nih.gov/pubmed/21201877 http://dx.doi.org/10.1107/S1600536808004741 |
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