Poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(II)]

The asymmetric unit of the title compound, [Ba(C(6)H(2)N(3)O(7))(2)(H(2)O)(4)](n), consists of a barium ion coordinated by two nitrophenolate ligands and four water mol­ecules. Barium is deca­coordinated by O atoms. These units are linked together through bridging nitro groups to form a one-dimensio...

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Detalles Bibliográficos
Autores principales: Vesta, C., Uthrakumar, R., Jerome Das, S., Varghese, Babu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960753/
https://www.ncbi.nlm.nih.gov/pubmed/21201848
http://dx.doi.org/10.1107/S1600536808002961
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author Vesta, C.
Uthrakumar, R.
Jerome Das, S.
Varghese, Babu
author_facet Vesta, C.
Uthrakumar, R.
Jerome Das, S.
Varghese, Babu
author_sort Vesta, C.
collection PubMed
description The asymmetric unit of the title compound, [Ba(C(6)H(2)N(3)O(7))(2)(H(2)O)(4)](n), consists of a barium ion coordinated by two nitrophenolate ligands and four water mol­ecules. Barium is deca­coordinated by O atoms. These units are linked together through bridging nitro groups to form a one-dimensional polymeric chain. The three-dimensional packing is facilitated through hydrogen-bonding inter­actions mediated through water mol­ecules. The coordination distances around Ba vary from 2.728 (4) to 3.138 (5) Å. The crystal sample, on exposure to air at room temperature for many days, slowly loses the water and peels out as filaments.
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spelling pubmed-29607532010-12-30 Poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(II)] Vesta, C. Uthrakumar, R. Jerome Das, S. Varghese, Babu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ba(C(6)H(2)N(3)O(7))(2)(H(2)O)(4)](n), consists of a barium ion coordinated by two nitrophenolate ligands and four water mol­ecules. Barium is deca­coordinated by O atoms. These units are linked together through bridging nitro groups to form a one-dimensional polymeric chain. The three-dimensional packing is facilitated through hydrogen-bonding inter­actions mediated through water mol­ecules. The coordination distances around Ba vary from 2.728 (4) to 3.138 (5) Å. The crystal sample, on exposure to air at room temperature for many days, slowly loses the water and peels out as filaments. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960753/ /pubmed/21201848 http://dx.doi.org/10.1107/S1600536808002961 Text en © Vesta et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vesta, C.
Uthrakumar, R.
Jerome Das, S.
Varghese, Babu
Poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(II)]
title Poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(II)]
title_full Poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(II)]
title_fullStr Poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(II)]
title_full_unstemmed Poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(II)]
title_short Poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(II)]
title_sort poly[tetra­aqua­bis(μ(2)-2,4,6-trinitro­phenolato)barium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960753/
https://www.ncbi.nlm.nih.gov/pubmed/21201848
http://dx.doi.org/10.1107/S1600536808002961
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AT varghesebabu polytetraaquabism2246trinitrophenolatobariumii

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