Poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(III)]

The title compound, [Tm(4)(C(8)H(4)O(4))(6)(H(2)O)(2)](n), has been synthesized hydro­thermally. The asymmetric unit has four unique Tm(III) ions that are six-, seven-, eight- and nine-coordinate. The cations are inter­connected by bridging benzene-1,2-dicarboxyl­ate (BDC) anions to form an infinite...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Guo-Ming, Duan, Chun-Sheng, Liu, Hui-Luan, Li, Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960755/
https://www.ncbi.nlm.nih.gov/pubmed/21201858
http://dx.doi.org/10.1107/S1600536808003620
_version_ 1782188816923099136
author Wang, Guo-Ming
Duan, Chun-Sheng
Liu, Hui-Luan
Li, Hui
author_facet Wang, Guo-Ming
Duan, Chun-Sheng
Liu, Hui-Luan
Li, Hui
author_sort Wang, Guo-Ming
collection PubMed
description The title compound, [Tm(4)(C(8)H(4)O(4))(6)(H(2)O)(2)](n), has been synthesized hydro­thermally. The asymmetric unit has four unique Tm(III) ions that are six-, seven-, eight- and nine-coordinate. The cations are inter­connected by bridging benzene-1,2-dicarboxyl­ate (BDC) anions to form an infinite two-dimensional framework, in which the BDC ligands adopt three different coordination modes. Adjacent sheets are further packed to form a three-dimensional supra­molecular framework through O—H⋯O hydrogen bonds.
format Text
id pubmed-2960755
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29607552010-12-30 Poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(III)] Wang, Guo-Ming Duan, Chun-Sheng Liu, Hui-Luan Li, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Tm(4)(C(8)H(4)O(4))(6)(H(2)O)(2)](n), has been synthesized hydro­thermally. The asymmetric unit has four unique Tm(III) ions that are six-, seven-, eight- and nine-coordinate. The cations are inter­connected by bridging benzene-1,2-dicarboxyl­ate (BDC) anions to form an infinite two-dimensional framework, in which the BDC ligands adopt three different coordination modes. Adjacent sheets are further packed to form a three-dimensional supra­molecular framework through O—H⋯O hydrogen bonds. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960755/ /pubmed/21201858 http://dx.doi.org/10.1107/S1600536808003620 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wang, Guo-Ming
Duan, Chun-Sheng
Liu, Hui-Luan
Li, Hui
Poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(III)]
title Poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(III)]
title_full Poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(III)]
title_fullStr Poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(III)]
title_full_unstemmed Poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(III)]
title_short Poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(III)]
title_sort poly[diaqua­penta­kis(μ(4)-benzene-1,2-dicarboxyl­ato)(μ(3)-benzene-1,2-dicarboxyl­ato)tetra­thulium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960755/
https://www.ncbi.nlm.nih.gov/pubmed/21201858
http://dx.doi.org/10.1107/S1600536808003620
work_keys_str_mv AT wangguoming polydiaquapentakism4benzene12dicarboxylatom3benzene12dicarboxylatotetrathuliumiii
AT duanchunsheng polydiaquapentakism4benzene12dicarboxylatom3benzene12dicarboxylatotetrathuliumiii
AT liuhuiluan polydiaquapentakism4benzene12dicarboxylatom3benzene12dicarboxylatotetrathuliumiii
AT lihui polydiaquapentakism4benzene12dicarboxylatom3benzene12dicarboxylatotetrathuliumiii

Ejemplares similares