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4-Chloro-2-[(E)-({4-[N-(3,4-dimethylisoxazol-5-yl)sulfamoyl]phenyl}iminio)methyl]phenolate
The title compound, C(18)H(16)ClN(3)O(4)S, is a Schiff base ligand in which the H atom of the hydroxy group has moved to the N atom of the imine group, resulting in a zwitterion. The structure is stabilized by an intramolecular (N—H⋯O) and five intermolecular (C—H⋯O, C—H⋯N and N—H⋯O) hydrogen bon...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960758/ https://www.ncbi.nlm.nih.gov/pubmed/21201966 http://dx.doi.org/10.1107/S1600536808005321 |
Sumario: | The title compound, C(18)H(16)ClN(3)O(4)S, is a Schiff base ligand in which the H atom of the hydroxy group has moved to the N atom of the imine group, resulting in a zwitterion. The structure is stabilized by an intramolecular (N—H⋯O) and five intermolecular (C—H⋯O, C—H⋯N and N—H⋯O) hydrogen bonds. The molecules are linked to each other by hydrogen bonds and form a three-dimensional polymeric network. In addition, the aromatic rings are also involved in π–π interactions [centroid–centroid distance between aromatic rings = 3.7525 (11) Å]. |
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